期刊
MATERIALS
卷 15, 期 9, 页码 -出版社
MDPI
DOI: 10.3390/ma15093046
关键词
aluminum oxide; aluminum waste can; characterization; sol-gel synthesis
类别
资金
- Universiti Malaysia Pahang
Aluminum waste-can management in Malaysia has become a significant environmental and public health issue. This study successfully synthesized high-quality alumina from the collected waste-cans using the sol-gel technique. The synthesized alumina exhibited excellent surface-area characteristics and functional properties comparable with commercially available brands.
Aluminum waste-can management in Malaysia has recently become a serious environmental and public health issue, particularly in metropolitan areas. This has prompted the need to valorize these waste-cans into value-added products using the most economical and environmentally friendly techniques. In this study, the sol-gel technique was used to synthesize high-quality alumina from the aluminum waste-cans collected. From this method, the observed peaks of the synthesized alumina were identified as diaspore (alpha-AlO(OH)), boehmite (gamma-AlO(OH)), aluminum oxide, or gamma-alumina (gamma-Al2O3) crystalline structure and corundum. The morphological configuration, microstructure, and functional group properties of the synthesized alumina were evaluated. All the synthesized alumina exhibited a non-spherical shape and appeared to have hexagonal-like shape particles. Moreover, the XRD patterns of the synthesized alumina AL-6-30 and AL-12-30 exhibited a small angle (1-10 degrees) with no XRD peak, which indicated a mesoporous pore structure with no long-range order. The overall results of gamma-alumina synthesized from the aluminum waste-cans showed an optimal condition in producing a highly structured gamma-alumina with excellent surface-area characteristics. The synthesized alumina exhibited stronger and highly crystalline functional characteristics almost comparable with the commercially available brands on the market.
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