☆ 4.6 Review

Quo Vadis, Nanothermite? A Review of Recent Progress

MATERIALS (2022)

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Article Engineering, Environmental

Spark sensitivity and light signature mitigation of an Al/SnO2 nanothermite by the controlled addition of a conductive polymer

Virginie Goetz et al.

Summary: The study focused on incorporating a conductive polymer polyaniline (PAni) into Al/SnO2 energetic nanocomposites through two different methods to enhance performance and reduce sensitivity. Results showed that intimate integration of the polymer with the oxide can effectively decrease the sensitivity of the energetic composition, making it safer while improving reaction speed and combustion properties.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Thermodynamics

Direct ink writing of nAl/pCuO/HPMC with outstanding combustion performance and ignition performance

Jianyong Xu et al.

Summary: Direct ink writing has enabled the preparation of energetic inks like nAl/pCuO/HPMC, which significantly influence printing accuracy and reaction performance. The content of HPMC in the ink is a key factor that affects ignition performance and pressure behavior.

COMBUSTION AND FLAME (2022)

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Article Engineering, Multidisciplinary

Ignition of nanothermites by a laser diode pulse

Alexander Yu Dolgoborodov et al.

Summary: This study investigates the laser ignition and combustion of nanothermites based on aluminum and copper, bismuth, and molybdenum oxides through experimental investigation. The research proposes new assumptions regarding the ignition mechanism and burning process of nanothermites.

DEFENCE TECHNOLOGY (2022)

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Article Engineering, Multidisciplinary

Combustion characteristic and aging behavior of bimetal thermite powders

Hong-qi Nie et al.

Summary: In this study, bimetal thermite powders were produced by investigating combustion characteristic and aging behavior of aluminum/iron oxide nanothermite mixtures in the presence of micron-scale nickel. The results showed that the inclusion of nickel led to a higher alumina content and finer particle sizes in the combustion residue, indicating more complete combustion and reduced agglomeration. Moreover, the nanothermite mixtures containing nickel demonstrated better aging resistance with less reduction in heat of combustion compared to those without nickel.

DEFENCE TECHNOLOGY (2021)

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Article Engineering, Multidisciplinary

Thermodynamics and performance of Al/CuO nanothermite with different storage time

Cheng-ai Wang et al.

Summary: The storage stability and activation energy changes of Al/CuO nanothermite stored for different periods of time were systematically researched in this study. It was found that long-term storage significantly reduced the ignition and combustion properties of the nanothermite.

DEFENCE TECHNOLOGY (2021)

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Article Polymer Science

Colloid Thermite Nanostructure: A Novel High Energy Density Material for Enhanced Explosive Performance

Sherif Elbasuney et al.

Summary: Nanothermites exhibit vigorously-exothermic reactions and enhanced reaction rates at nanoscale. The integration of oxide NPs with aluminium NPs in TNT can significantly improve its destructive effect, with CuO/Al mixture offering the highest increase at 35%. The low ignition temperature and high oxygen release rate of nanoscopic CuO/Al play a crucial role in this enhancement.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Perfluoroalkyl Acid-Functionalized Aluminum Nanoparticles for Fluorine Fixation and Energy Generation

Wanjun Zhao et al.

Summary: In this study, the surface functionalization of aluminum nanoparticle using perfluoroalkyl acids improved its energy performances and fluorine fixation ratio. The combustion characteristics and heat release of nAl/PFAAs were enhanced in different atmospheres. The reaction mechanism involved the corrosion of oxide layer, generation of fluorocarbons, and fluorination of exposed AI.

ACS APPLIED NANO MATERIALS (2021)

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Article Chemistry, Applied

Determination of JWL parameters from underwater explosion test of spherical explosives by continuous velocity probe

Kebin Li et al.

Summary: This paper presents a new method for determining the Jones-Wilkins-Lee equation of state (JWL-EOS) through underwater explosion tests with spherical charges. Through field tests using RDX, the JWL-EOS parameters were successfully adjusted to plot the adiabatic curves of pressure versus relative volume.

JOURNAL OF ENERGETIC MATERIALS (2021)

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Article Materials Science, Composites

Study on Indium (III) Oxide/Aluminum Thermite Energetic Composites

Pierre Gibot et al.

Summary: The study focused on the use of indium (III) oxide nanoparticles as oxidizer in the preparation of nanothermites and evaluated their performance characteristics and combustion velocity, as well as spark sensitivity. Experimental results showed that the Al/In2O3 nanothermite was insensitive to impact and friction stimuli, but extremely sensitive to spark.

JOURNAL OF COMPOSITES SCIENCE (2021)

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Article Thermodynamics

Superior performance of quaternary NC/GO/Al/KClO4 nanothermite for high speed impulse small-scale propulsion applications

Ahmed Fahd et al.

Summary: By introducing nitrocellulose (NC) into nanothermites, significant enhancements in combustion performance, including thrust output, specific and volumetric impulses, and total heat released, are achieved. Thermal analysis suggests that the addition of NC introduces another step in the GO/Al/KClO4 reaction, with the liquid-liquid phase diffusion reaction increasing with NC percentage. Electrospinning is a simple technique for preparing quaternary nanothermites that results in improved combustion performance and enhanced suitability for small-scale propulsion applications.

COMBUSTION AND FLAME (2021)

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Article Thermodynamics

Fabrication of high electrostatic safety metastable Al/CuO nanocomposites doped with nitro-functionalized graphene with fast initiation ability and tunable reaction performance

Yueting Wang et al.

Summary: This paper investigates the catalytic effects of nitrated graphene oxide (NGO) as an additive on Al/CuO nanocomposites, showing that adding a certain amount of NGO can enhance the reaction heat and pressurization rate. The special structure of NGO allows for tunable ignition temperature and propagation velocity of the composites, while its high electrical conductivity improves the electrostatic discharge safety of the composites.

COMBUSTION AND FLAME (2021)

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Article Physics, Condensed Matter

Study of energy release in Fe2O3/Al nano-thermite with graphene as an additional fuel

Priya Thakur et al.

Summary: In this study, Fe2O3/Al nano-thermite with different weight fractions of multi-layered graphene (MLG) nanoplatelets were synthesized using a physical mixing technique. It was found that increasing the content of MLG in the nano-thermite resulted in higher exothermic enthalpy and lower ignition temperature and activation energy.

PHYSICA B-CONDENSED MATTER (2021)

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Article Chemistry, Applied

On the Pressure Generated by Thermite Reactions Using Stress-Altered Aluminum Particles

Alan Williams et al.

Summary: This study examines pressure build-up and decay in thermite upon impact ignition and interprets reactivity based on the holistic pressure history. Results reveal that the rate of pressure development is directly correlated with the reactivity of the thermite, with lower peak pressure corresponding to higher thermite reactivity.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2021)

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Article Chemistry, Physical

Facile synthesis of high tightly ordered Al/CuO core-shell nanowire arrays and the effect of surface density on combustion

Haifeng Yang et al.

Summary: The CuO nanowires prepared by electrochemical and chemical etching methods have high surface density and a homogeneous structure, beneficial for the contact between Al and CuO. The nano-thermite prepared by electrochemical-sputtering method shows 8 times heat release per unit area compared to the chemical-sputtering method, with significantly reduced activation energy and easier ignition.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Materials Science, Ceramics

Effect of CuO on the thermal kinetics and combustion properties of Al/MoO3 thermite prepared by ball milling

Jialin Chen et al.

Summary: The addition of CuO significantly increases the heat release and decreases the exothermic peak temperature of Al/MoO3 thermite, but when the mass fraction of CuO reaches a certain level, violent explosion reactions occur.

CERAMICS INTERNATIONAL (2021)

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Article Engineering, Chemical

Energetic metastable Al/CuO/PVDF/RDX microspheres with enhanced combustion performance

Lei Xiao et al.

Summary: Nanothermites have shown promising potential in micro propellant applications due to their faster reaction rate, higher energy-release efficiency, and improved combustion performance. By utilizing electrospray technology to assemble Al/CuO/PVDF microspheres incorporating high explosive RDX, the composite microspheres exhibit enhanced thermal and combustion performance compared to physical mixtures, with shorter delay time, burning time, and higher pressure. Additionally, the combustion performance of the microspheres is mainly influenced by the content of RDX, suggesting that the electrospray technology and RDX addition are effective methods to prepare nanothermites with enhanced reactivity.

CHEMICAL ENGINEERING SCIENCE (2021)

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Article Materials Science, Multidisciplinary

Combustion/decomposition characteristics of 3D-printed Al/CuO, Al/ Fe2O3, Al/Bi2O3 and Al/PTFE hollow filaments

Lin Zhong et al.

Summary: This study explores the preparation of structural energetic materials (EMs) through 3D printing of hollow filaments, showing that they exhibit shorter unsteady combustion time and increased steady flame propagation rate. The hollow filaments with Al/CuO/F2311 formula demonstrate the lowest thermal decomposition onset temperature and the best gas-generation performance compared to other composites.

MATERIALS CHEMISTRY AND PHYSICS (2021)

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Article Engineering, Electrical & Electronic

Bio-inspired metastable intermolecular nanothermite composite based on Manganese dioxide/Polydopamine/Aluminium

Sherif Elbasuney et al.

Summary: This study presents a method for achieving intimate mixing between MnO2 NPs and Al NPs through surface modification. Surface modification of Al NPs with PDA was accomplished via in situ polymerization, leading to successful preparation of MnO2/PDA/Al nanocomposite.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

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Article Chemistry, Applied

New Detonating Compositions from Ammonium Dinitramide

Marc Comet et al.

Summary: This article introduces a new family of detonating compositions using ammonium dinitramide as an explosive oxidizer and red phosphorus or titanium hydride as fuels. These compositions have high explosion heats, detonation velocities, and run to detonation distances, insensitive to electrostatic discharge but sensitive to impact and friction, and can efficiently initiate the detonation of high explosives. They are seen as green substitutes for primary explosives containing heavy metals.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2021)

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Article Instruments & Instrumentation

The development of an on-chip microinitiator with a built-in safety-and-arming device

Tengjiang Hu et al.

Summary: A novel MEMS initiator with a built-in safety-and-arming device is introduced, utilizing a movable barrier controlled by the MEMS S&A device to switch between armed and safe modes. Experimental results show the effectiveness and performance of the device in generating output displacement and containing explosion energy.

REVIEW OF SCIENTIFIC INSTRUMENTS (2021)

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Article Materials Science, Multidisciplinary

Experimental and numerical investigations of the effect of charge density and scale on the heat transfer behavior of Al/CuO nano-thermite

Yueting Wang et al.

Summary: The experimental and theoretical results indicate that gas flow seepage is a critical factor affecting the heat transfer process of Al/CuO nano-thermite in burn tubes, leading to a decrease in propagation velocity with increasing charge density. Introducing a certain amount of NC into the component can improve reactivity and increase gas production and pressurization capacity, significantly enhancing the propagation velocity of Al/CuO nanothermite under constraint conditions. Additionally, the increase in relative heat loss with decreasing tube diameter is the main reason for the decrease in propagation velocity, and the dimensionless parameter theta can be used to analyze the heat loss coefficient under different charge diameters.

VACUUM (2021)

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Article Materials Science, Multidisciplinary

Thermal behavior and combustion performance of Al/Bi2O3 nano thermites with the effect of potassium perchlorate

Shi Li et al.

Summary: The addition of potassium perchlorate (KClO4) was found to enhance the performance of Al/Bi2O3 nano thermites, with the highest heat release observed at 10 wt% KClO4 and the lowest activation energy at 30 wt% KClO4. This study provides a method to increase heat release or reduce activation energy by controlling the amount of added KClO4.

MATERIALS RESEARCH EXPRESS (2021)

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Article Thermodynamics

Fabrication of gradient structured HMX/Al and its combustion performance

Qianqian He et al.

Summary: The research shows that gradient structured HMX/Al composite materials designed and fabricated using 3D printing technology have controllable burning rates and higher energy output, with the burning rate of each component in the gradient structure higher than that of the normal structure.

COMBUSTION AND FLAME (2021)

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Article Polymer Science

Polypyrrole material for the electrostatic discharge sensitivity mitigation of Al/SnO2 energetic composites

Pierre Gibot et al.

Summary: This study investigated the use of doped-polypyrrole conducting polymer in Al/SnO2 nanothermite to reduce its electrostatic discharge sensitivity, showing a gradual desensitization of ESD with increasing polypyrrole content. The reactive properties of polypyrrole-enriched nanothermite were verified, indicating an acceptable reactive behavior. This is the first report of successful addition of doped-polypyrrole conducting polymer in energetic nanocomposites.

JOURNAL OF APPLIED POLYMER SCIENCE (2021)

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Article Engineering, Electrical & Electronic

Novel electrophoretic assembly design of nano-aluminum@tungsten trioxide (nano-Al@WO3) energetic coating with controllable exothermic performance

Xiaogang Guo et al.

Summary: This study developed the electrophoretic assembly technique for designing nano-Al@WO3 energetic coating, with even distribution of nanoparticles achieved and the heat-release process of the product highly controlled by adjusting the solid loading concentration ratio. The method shows great potential for constructing or designing various energetic nanocomposite coatings with wide applications.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

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Article Chemistry, Applied

Synthesis and Characterization of Tertiary Nanothermite CNMs/Al/KClO4 with Enhanced Combustion Characteristics

Ahmed Fahd et al.

Summary: This study evaluated the impact of different carbon nanomaterials on the combustion behavior of nanothermite and found that adding graphene oxide significantly improved the total heat released and ignition characteristics.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2021)

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Article Nanoscience & Nanotechnology

Carbon Fibers Enhance the Propagation of High Loading Nanothermites: In Situ Observation of Microscopic Combustion

Haiyang Wang et al.

Summary: This study demonstrates that adding carbon fibers into Al/CuO nanothermite sticks can significantly improve burn rate and heat flux, with the carbon fibers intercepting ejected hot agglomerates near the burning surface to enhance heat feedback. These approaches have the potential to enhance propagation and reduce two-phase flow losses.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

Smart Electromagnetic Thermites: GO/rGO Nanoscale Thermite Composites with Thermally Switchable Microwave Ignitability

Stuart J. Barkley et al.

Summary: This study presents the development of a novel graphene oxide nanoscale thermite composite with thermally tunable microwave ignitability, achieving thermally switchable microwave ignitability by incorporating graphene oxide.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Engineering, Environmental

Unexpected enhanced reactivity of aluminized nanothermites by accelerated aging

Tao Wu et al.

Summary: The study of aging processes in powdered nanothermites reveals the high complexity, as it not only leads to a consumption of the heat reservoir, but also results in a modification of the Al/oxidizer interface morphology and chemistry. The annealing experiments show that Al/CuO and Al/Fe2O3 thermites exhibit increased reaction and pressurization rates after annealing at 200 degrees C in air and 400 degrees C in argon, while the same nanothermites annealed at 400 degrees C in air feature reduced reactivity due to over-oxidations of the aluminum core and the formation of crystalline alumina shell.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Thermodynamics

Modelling reaction propagation for Al/CuO nanothermite pellet combustion

Joseph Mark Epps et al.

Summary: A continuum-scale model for the combustion of consolidated nanothermite pellets is introduced. Sensitivity analysis reveals the relative importance of modeling parameters for combustion regimes, and a non-dimensionalization approach is proposed to establish a linear scaling between the burn rate and Peclet number, achieving consistency between numerical results and experimental data. The study identifies a transition between conduction- and advection-dominated combustion based on the transient burn rate of the nanothermite pellet combustion.

COMBUSTION AND FLAME (2021)

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Article Thermodynamics

Connecting agglomeration and burn rate in a thermite reaction: Role of oxidizer morphology

Haiyang Wang et al.

Summary: Agglomeration of aluminum particles is commonly observed in solid propellants and pyrotechnics, playing a key role in combustion performance. In a study on Al/CuO reaction, using microwire oxidizer resulted in higher propagation velocities and agglomerate sizes closer to nanoparticles. Adding polymer slowed down burn rates, allowing detailed observation of agglomeration process.

COMBUSTION AND FLAME (2021)

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Article Thermodynamics

Alcohol-thermal synthesis of approximately core-shell structured Al@CuO nanothermite with improved heat-release and combustion characteristics

Kaiwen Shi et al.

Summary: Metastable intermolecular composites (MICs), also known as nanothermites, are synthesized using an alcohol-thermal technique in this study to create Al@CuO MICs with enhanced energy release characteristics. The research findings indicate that Al@CuO exhibits lower apparent activation energy for solid-state interfacial reaction and higher energy output, with a slightly fuel-rich formulation being preferred for combustion efficiency.

COMBUSTION AND FLAME (2021)

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Article Thermodynamics

Probing boron thermite energy release at rapid heating rates

Jennifer L. Gottfried et al.

Summary: Boron is a promising fuel for energetic materials due to its high energy density when combined with CuO and Bi2O3 in thermite reactions. The application of LASEM technique has enabled the quantification of energy release and excitation temperatures of B/metal oxide samples on microsecond and millisecond timescales. The enhancement of ignition in these composites contributes to the early-time energy release, as shown by relative measurements in agreement with bomb calorimetry and DSC analysis. Additionally, the strong affinity of CuO for both B and Bi2O3 leads to a synergetic enhancement effect in the binary metal oxide mixture.

COMBUSTION AND FLAME (2021)

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Article Thermodynamics

Rational design of gradient structured fluorocarbon/Al composites towards tunable combustion performance

Yaofeng Mao et al.

Summary: The gradient structured PTFE/Al composite material, designed and constructed using 3D printing technology, allows for precise control of combustion reaction and energy output performance. By varying the diameter and mass gradient, the material exhibits improved reaction heat and burning rate.

COMBUSTION AND FLAME (2021)

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Article Thermodynamics

Tuning the reactivity and energy release rate of I2O5 based ternary thermite systems

Feiyu Xu et al.

Summary: This study investigates the tunability of I2O5 based nanothermites by exploring various fuel compositions, demonstrating how the combustion properties can be adjusted by changing the composition of ternary systems. The introduction of Ti or Si into the Al/I2O5 system shifts the reaction initiation mechanism, leading to a correlation between energy release rate and burn time rather than flame temperature. This research provides a new approach to tune the reactivity and energy release rate of I2O5 based nanothermites without affecting energy density.

COMBUSTION AND FLAME (2021)

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Article Chemistry, Applied

Submicron Potassium Perchlorate: a Key Component to Reach Detonation in Binary Mixtures with Titanium Hydride

Marc Comet et al.

Summary: The research introduced a new type of pyrotechnic composition THKP, formulated from submicron KClO4 and TiH2, with fast deflagration velocity and high stability. The transition to detonation was observed in THKP, whereas conventional THKP prepared from micron-sized KClO4 did not exhibit this transition.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2021)

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Article Chemistry, Physical

Exothermic behaviour of aluminium and graphene as a fuel in Fe2O3 based nanothermite

Priya Thakur et al.

Summary: The study focused on the influence of multi-layer graphene (MLG) and aluminum as fuel in Al/Fe2O3 and MLG/Fe2O3 nanothermites, prepared by physical mixing and ultrasonication techniques. Characterization techniques included XRD, FESEM, EDS, FTIR, Raman spectroscopy, and DSC to study structural and energy release properties, revealing intact phases during synthesis, undeteriorated graphene aromatic structure, and exothermic energy release values of 215 J/g and 1640 J/g for Al/Fe2O3 and MLG/Fe2O3, respectively.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES (2021)

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Article Chemistry, Multidisciplinary

Assembling Hybrid Energetic Materials with Controllable Interfacial Microstructures by Electrospray

Lihong Chen et al.

Summary: Constructing hybrid energetic materials (HEMs) using electrospray to assemble Al/CuO nanothermites and CL-20 explosives into various morphologies in different solvent systems can regulate the reactivity of energetic composites. The interfacial microstructures play a crucial role in determining the combustion performance and pressurization characteristics of the HEMs. The results show that granular HEMs exhibit high gas generation and pressurization rate, while clay-like HEMs with nitrocellulose fibers weakens the reactivity to some extent.

ACS OMEGA (2021)

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Article Nanoscience & Nanotechnology

Optimizing the Interfaces of Energetic Textiles with Perfluorinated Oligomer-Coated Aluminum Nanoparticles: Implications for Metastable Intermolecular Composites

Nathan J. Weeks et al.

Summary: Metal powders with nanometer-sized particles can greatly enhance energetic performance due to increased specific surface area. Optimizing the interface between metal fuel and polymer matrix is crucial for achieving maximum weight percent loading of metal nanoparticles.

ACS APPLIED NANO MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Surface modification and functionalization of powder materials by atomic layer deposition: a review

Yiyun Hu et al.

Summary: Powder materials are industrially important with surface modification being essential for enhanced performances. Atomic layer deposition (ALD) is a cutting-edge technology used for precise thin film growth on powder materials, enabling various applications in different fields.

RSC ADVANCES (2021)

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Article Chemistry, Multidisciplinary

High-energy Al/graphene oxide/CuFe2O4 nanocomposite fabricated by self-assembly: Evaluation of heat release, ignition behavior, and catalytic performance

Jinghua Wang et al.

Summary: In this study, a high-energy Al/GO/CuFe2O4 nanocomposite was successfully fabricated through self-assembly guided by negatively charged graphene oxide. The optimized equivalence ratio resulted in superior heat release and ignition characteristics compared to known thermites. Additionally, the nanocomposite effectively catalyzed the thermal decomposition of RDX and AP, reducing their decomposition temperatures and activation energies.

ENERGETIC MATERIALS FRONTIERS (2021)

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Article Thermodynamics

Preparation and thermal decomposition properties of nitrated graphene oxide (NGO)/RDX nano-energetic composites

Shen Yuan et al.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY (2020)

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Article Chemistry, Applied

Aluminium/tin (IV) oxide thermite composite: sensitivities and reaction propagation

Pierre Gibot et al.

JOURNAL OF ENERGETIC MATERIALS (2020)

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Article Chemistry, Applied

OZM Ball Drop Impact Tester (BIT-132) vs. BAM Standard Method-a Comparative Investigation

Michael S. Gruhne et al.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2020)

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Article Engineering, Environmental

Energetic composites based on nano-Al and energetic coordination polymers (ECPs): The father-son effect of ECPs

Xiaoxia Ma et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Polymer Science

SnO2-polyaniline composites for the desensitization of Al/SnO2 thermite composites

Pierre Gibot et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2020)

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Article Nanoscience & Nanotechnology

From nanoparticles to on-chip 3D nanothermite: electrospray deposition of reactive Al/CuO@NC onto semiconductor bridge and its application for rapid ignition

Ji Dai et al.

NANOTECHNOLOGY (2020)

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Article Thermodynamics

An effective way to enhance energy output and combustion characteristics of Al/PTFE

Jun Wang et al.

COMBUSTION AND FLAME (2020)

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Article Thermodynamics

Experimental observation of the heat transfer mechanisms that drive propagation in additively manufactured energetic materials

Dylan J. Kline et al.

COMBUSTION AND FLAME (2020)

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Article Engineering, Industrial

Al-NiO energetic composites as heat source for joining silicon wafer

Hongtao Sui et al.

JOURNAL OF MATERIALS PROCESSING TECHNOLOGY (2020)

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Article Chemistry, Analytical

A Facile Preparation and Energetic Characteristics of the Core/Shell CoFe2O4/Al Nanowires Thermite Film

Chunpei Yu et al.

MICROMACHINES (2020)

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Article Chemistry, Multidisciplinary

Thermal Decomposition Behavior and Thermal Safety of Nitrocellulose with Different Shape CuO and Al/CuO Nanothermites

Ergang Yao et al.

NANOMATERIALS (2020)

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Article Chemistry, Multidisciplinary

Controllable Electrically Guided Nano-Al/MoO3 Energetic-Film Formation on a Semiconductor Bridge with High Reactivity and Combustion Performance

Xiaogang Guo et al.

NANOMATERIALS (2020)

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Article Chemistry, Multidisciplinary

Hydrothermal Synthesis of Hematite Nanoparticles Decorated on Carbon Mesospheres and Their Synergetic Action on the Thermal Decomposition of Nitrocellulose

Abdenacer Benhammada et al.

NANOMATERIALS (2020)

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Article Engineering, Chemical

A Favorable Improvement in Reactivity between n-Al and Sheet-like Porous CuO as a Nanoenergetic Composite by Graphene Oxide Additives

Yajie Chen et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Engineering, Environmental

Sponge-like Al/PVDF films with laser sensitivity and high combustion performance prepared by rapid phase inversion

Suhang Chen et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Multidisciplinary

Layered Al/CuO Thin Films for Tunable Ignition and Actuations

Ludovic Salvagnac et al.

NANOMATERIALS (2020)

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Article Chemistry, Applied

The Effect of Detonator Shell Materials on Detonation Calorimetry Results

Ondrej Nemec et al.

CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Preparation and Characterization of Silicon-Metal Fluoride Reactive Composites

Siva Kumar Valluri et al.

NANOMATERIALS (2020)

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Review Nanoscience & Nanotechnology

Recent trends in nanothermites: Fabrication, characteristics and applications

Shruti Kabra et al.

NANO EXPRESS (2020)

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Article Chemistry, Multidisciplinary

Preparation and Characterization of Al/HTPB Composite for High Energetic Materials

Alexander Vorozhtsov et al.

NANOMATERIALS (2020)

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Review Chemistry, Applied

Review of Gasless Pyrotechnic Time Delays

Walter W. Focke et al.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2019)

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Article Mechanics

Deflagration-to-detonation transition in Bullseye powder

T. Miner et al.

SHOCK WAVES (2019)

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Article Chemistry, Multidisciplinary

Direct Writing of a 90 wt% Particle Loading Nanothermite

Haiyang Wang et al.

ADVANCED MATERIALS (2019)

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Article Nanoscience & Nanotechnology

Core@Double-Shell Structured Energetic Composites with Reduced Sensitivity and Enhanced Mechanical Properties

Congmei Lin et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Thermodynamics

Pre-stressing aluminum nanoparticles as a strategy to enhance reactivity of nanothermite composites

Rohit J. Jacob et al.

COMBUSTION AND FLAME (2019)

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Article Chemistry, Multidisciplinary

An Electrospun Preparation of the NC/GAP/Nano-LLM-105 Nanofiber and Its Properties

Tingting Luo et al.

NANOMATERIALS (2019)

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Article Engineering, Multidisciplinary

Nanothermite colloids: A new prospective for enhanced performance

M. Gaber Zaky et al.

DEFENCE TECHNOLOGY (2019)

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Article Nanoscience & Nanotechnology

Precisely Controlled Reactive Multilayer Films with Excellent Energy Release Property for Laser-Induced Ignition

Wei Guo et al.

NANOSCALE RESEARCH LETTERS (2019)

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Article Chemistry, Multidisciplinary

Nanometer Ammonium Perchlorate and Ammonium Nitrate Prepared with 2D Network Structure via Rapid Freezing Technology

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Microwave plasma enhancement of multiphase flames: On-demand control of solid propellant burning rate

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COMBUSTION AND FLAME (2019)

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Nanothermites: A short Review. Factsheet for Experimenters, Present and Future Challenges

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2019)

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Silver ferrite: a superior oxidizer for thermite-driven biocidal nanoenergetic materials

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Performance of iodine oxides/iodic acids as oxidizers in thermite systems

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Tuning the ignition and combustion properties of nanoenergetic materials by incorporating with carbon black nanoparticles

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COMBUSTION AND FLAME (2018)

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Tuning the morphological, ignition and combustion properties of micron-Al/CuO thermites through different synthesis approaches

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COMBUSTION AND FLAME (2018)

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High speed 2-dimensional temperature measurements of nanothermite composites: Probing thermal vs. Gas generation effects

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JOURNAL OF APPLIED PHYSICS (2018)

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Treatment of military primary explosives wastewater containing lead styphnate (LS) and lead azide (LA) by mFe0-PS-O3 process

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Novel Colloidal Nanothermite Particles (MnO2/Al) for Advanced Highly Energetic Systems

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Ignition of Nanoscale Titanium/Potassium Perchlorate Pyrotechnic Powder: Reaction Mechanism Study

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Impact ignition and combustion of micron-scale aluminum particles pre-stressed with different quenching rates

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The Safety Properties of a Potential Kind of Novel Green Primary Explosive: Al/Fe2O3/RDX Nanocomposite

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Combustion Characteristics o f Physically Mixed 40 nm Aluminum/Copper Oxide Nanothermites Using Laser Ignition

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Formation of Additive-Containing Nanothermites and Modifications to their Friction Sensitivity

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Incomplete reactions in nanothermite composites

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High Heating Rate Reaction Dynamics of Al/CuO Nanolaminates by Nanocalorimetry-Coupled Time-of-Flight Mass Spectrometry

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MATERIALS LETTERS (2017)

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Review Chemistry, Applied

Comparison of Performance of Fast-Reacting Nanothermites and Primary Explosives

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2017)

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Electrostatic Discharge Sensitivity and Resistivity Measurements of Al Nanothermites and Their Fuel and Oxidant Precursors

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CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS (2017)

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Effect of additives on CuO/Al nanothermite properties

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Microwave-assisted plasma ignition in a constant volume combustion chamber

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Ignition and Combustion Characteristics of Nanoaluminum with Copper Oxide Nanoparticles of Differing Oxidation State

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Propellants Reactivity Enhancement with Nanothermites

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2016)

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Sulfates-Based Nanothermites: An Expanding Horizon for Metastable Interstitial Composites

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Energetic nanocomposites for detonation initiation in high explosives without primary explosives

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APPLIED PHYSICS LETTERS (2015)

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Modulation of the Reactivity of a WO3/Al Energetic Material with Graphitized Carbon Black as Additive

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Laboratory-Scale Method for Estimating Explosive Performance from Laser-Induced Shock Waves

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Persulfate salt as an oxidizer for biocidal energetic nano-thermites

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Combustion characterization and modeling of novel nanoenergetic composites of Co3O4/nAl

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Low Effective Activation Energies for Oxygen Release from Metal Oxides: Evidence for Mass-Transfer Limits at High Heating Rates

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Dependence of catalytic properties of Al/Fe2O3 thermites on morphology of Fe2O3 particles in combustion reactions

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Influence of exothermic chemical reactions on laser-induced shock waves

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Specimen size effect of explosive sensitivity under low velocity impact

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Ignition criterion and safety prediction of explosives under low velocity impact

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Fast-Impulse Nanothermite Solid-Propellant Miniaturized Thrusters

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Thermite powder ignition by localized microwaves

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2012)

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COMBUSTION AND FLAME (2011)

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Combustion characteristics of novel hybrid nanoenergetic formulations

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COMBUSTION AND FLAME (2011)

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A COMPARATIVE ANALYSIS OF THE TECHNICAL AND METROLOGICAL CHARACTERISTICS OF BOMB CALORIMETERS USED IN RUSSIA

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Temperature measurements of Al containing nano-thermite reactions using multi-wavelength pyrometry

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PROCEEDINGS OF THE COMBUSTION INSTITUTE (2011)

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Effects of fuel and oxidizer particle dimensions on the propagation of aluminum containing thermites

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PROCEEDINGS OF THE COMBUSTION INSTITUTE (2011)

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In situ microscopy of rapidly heated nano-Al and nano-Al/WO3 thermites

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APPLIED PHYSICS LETTERS (2010)

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Kinetic study of thermal- and impact-initiated reactions in Al-Fe2O3 nanothermite

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COMBUSTION AND FLAME (2010)

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Heat of combustion of tantalum-tungsten oxide thermite composites

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COMBUSTION AND FLAME (2010)

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Time-Resolved Mass Spectrometry of the Exothermic Reaction between Nanoaluminum and Metal Oxides: The Role of Oxygen Release

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JOURNAL OF PHYSICAL CHEMISTRY C (2010)

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Reduced-Sensitivity Nanothermites Containing Manganese Oxide Filled Carbon Nanofibers

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Combustion of Silicon/Teflon/Viton and Aluminum/Teflon/Viton Energetic Composites

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Simultaneous Pressure and Optical Measurements of Nanoaluminum Thermites: Investigating the Reaction Mechanism

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Modified Nanoenergetic Composites with Tunable Combustion Characteristics for Propellant Applications

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2010)

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Combustion Synthesis of Silicon Nanopowders

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INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS (2010)

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Characterization of Nanothermite Material for Solid-Fuel Microthruster Applications

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T-Jump/time-of-flight mass spectrometry for time-resolved analysis of energetic materials

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RAPID COMMUNICATIONS IN MASS SPECTROMETRY (2009)

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Nanoenergetic composites of CuO nanorods, nanowires, and Al-nanoparticles

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2008)

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Application of background oriented schlieren for quantitative measurements of shock waves from explosions

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SHOCK WAVES (2008)

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IGNITION CHARACTERISTICS OF NANOTHERMITE SYSTEMS

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Generation of fast propagating combustion and shock waves with copper oxide/aluminum nanothermite composites

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APPLIED PHYSICS LETTERS (2007)

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Development of nanothermite composites with variable electrostatic discharge ignition thresholds

Timothy Foley et al.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2007)

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Combustion of nanoscale Al/MoO3 thermite in microchannels

S. F. Son et al.

JOURNAL OF PROPULSION AND POWER (2007)

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Evidence for the transition from the diffusion-limit in aluminum particle combustion

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PROCEEDINGS OF THE COMBUSTION INSTITUTE (2007)

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Emission spectroscopy of flame fronts in aluminum suspensions

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PROCEEDINGS OF THE COMBUSTION INSTITUTE (2007)

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Nanoenergetic composite of mesoporous iron oxide and aluminum nanoparticles

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JOURNAL OF ENERGETIC MATERIALS (2006)

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Melt dispersion mechanism for fast reaction of nanothermites

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APPLIED PHYSICS LETTERS (2006)

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Combustion of environmentally altered molybdenum trioxide nanocomposites

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2006)

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OPTICS AND LASERS IN ENGINEERING (2006)

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Combustion velocities and propagation mechanisms of metastable interstitial composites

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JOURNAL OF APPLIED PHYSICS (2005)

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Synthesis and reactivity of a super-reactive metastable intermolecular composite formulation of Al/KMnO4

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ADVANCED MATERIALS (2005)

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Combustion behavior of highly energetic thermites: Nano versus micron composites

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2005)

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Nano-scale tungsten oxides for metastable intermolecular composites

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2004)

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Time-resolved spectral emission of deflagrating nano-Al and nano-MoO3 metastable interstitial composites

DS Moore et al.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2004)

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Nanomaterials for heterogeneous combustion

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PROPELLANTS EXPLOSIVES PYROTECHNICS (2004)

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Laser ignition of nanocomposite thermites

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COMBUSTION AND FLAME (2004)

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Enhanced photothermal effect in Si nanowires

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NANO LETTERS (2003)

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Use of a multiwavelength pyrometer in several elevated temperature aerospace applications

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