4.6 Article

Effects of Modified Inclusions and Precipitates Alloyed by Rare Earth Element on Corrosion and Impact Properties in Low Alloy Steel

期刊

ACTA METALLURGICA SINICA-ENGLISH LETTERS
卷 35, 期 10, 页码 1719-1730

出版社

CHINESE ACAD SCIENCES, INST METAL RESEARCH
DOI: 10.1007/s40195-022-01404-8

关键词

Rare earth element; Inclusion; Precipitate; Q355 low alloy steel; Corrosion resistance; Impact toughness

资金

  1. Open Project of State Key Laboratory of Advanced Special Steel
  2. Science and Technology Commission of Shanghai Municipality [19DZ2270200]
  3. National Natural Science Foundation of China [52031004]
  4. Shanghai Key Laboratory of Advanced Ferrometallurgy
  5. Shanghai University

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This study focuses on the influence of rare earth elements on the morphology and distribution of inclusions and precipitates in low alloy steel, and finds that the modification of rare earth inclusions significantly improves the corrosion properties and impact behavior of the steel.
This study has focused on the morphology and distribution of inclusions and precipitates modified by rare earth (RE) elements, which has a decisive influence on microstructure, corrosion properties and impact behaviors in Q355 low alloy steel. Characterized by the method of electrolytic extraction and ASPEX-scanning electron microscopy (ASPEX-SEM), small-sized spherical RE inclusions have been modified to replace elongated MnS and large-sized Al2O3. Q355RE steel after RE alloying has lower corrosion rate and higher value of alpha/gamma, due to the formation of stable and dense rust layers. Q355RE steel also exhibits better resistance to fracture at low temperature, owing to the presence of RE modification to inclusions and its effects on reducing crack initiation and propagation. Nano-scale RE precipitates containing sulfur and phosphorus is observed along grain boundaries by transmission electron microscopy (TEM). The purification of grain boundaries by RE is beneficial to the improvement of corrosion and impact properties.

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