期刊
TETRAHEDRON
卷 116, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2022.132809
关键词
Amination; Chlorosulfonyl isocyanate; a-1-C-Propyl-3,6-di-epi-nojirimycin; Polyhydroxyindolizidine alkaloids
资金
- National Research Foundation of Korea (NRF) [2020R1F1A1070288]
- National Research Foundation of Korea [2020R1F1A1070288] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The synthesis of a-1-C-propyl-3,6-di-epi-nojirimycin and Polyhydroxyindolizidine alkaloids from readily available a-methyl-D-mannopyranoside is described. The key step in this process involves a regioselective and diastereoselective amination of the anomeric acetal functionality using chlorosulfonyl isocyanate (CSI).
The synthesis of a-1-C-propyl-3,6-di-epi-nojirimycin and Polyhydroxyindolizidine alkaloids from readily available a-methyl-D-mannopyranoside is described. The key step in this process involves a regioselective and diastereoselective amination of anomeric acetal functionality using chlorosulfonyl isocyanate (CSI).(c) 2022 Elsevier Ltd. All rights reserved.
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