Phase-Selective Synthesis of Ruthenium Phosphide in Hybrid Structure Enables Efficient Hybrid Water Electrolysis Under pH-Universal Conditions

Hydrazine-assisted hybrid water electrolysis is an energy-saving approach to produce high-purity hydrogen, whereas the development of pH-universal bifunctional catalysts encounters a grand challenge. Herein, a phase-selective synthesis of ruthenium phosphide compounds hybrid with carbon forming pancake-like particles (denoted as RuxP/C-PAN, x = 1 or 2) is presented. The obtained RuP/C-PAN exhibits the highest catalytic activity among the control samples, delivering ultralow cell voltages of 0.03, 0.27, and 0.65 V to drive 10 mA cm(-2) using hybrid water electrolysis corresponding to pH values of 14, 7, and 0, respectively. Theoretical calculation deciphers that the RuP phase displays optimized free energy for hydrogen adsorption and reduced energy barrier for hydrazine dehydrogenation. This work may not only open up a new avenue in exploring universally compatible catalyst to transcend the limitation on the pH value of electrolytes, but also push forward the development of an energy-saving hydrogen generation technique based on emerging hybrid water electrolysis.

Automated summary

This study presents an energy-saving approach to produce high-purity hydrogen through hydrazine-assisted hybrid water electrolysis. By synthesizing the RuP/C-PAN catalyst, the water electrolysis reaction can be driven at ultralow voltage under different pH values, and the catalytic mechanism is explained. This research contributes to transcending the limitation on the pH value of electrolytes and advancing the development of an energy-saving hydrogen generation technique based on emerging hybrid water electrolysis.