期刊
SMALL
卷 18, 期 20, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202107697
关键词
coprecipitation; crystal growth; precursors; layered cathode materials; lithium-ion batteries
类别
资金
- National Natural Science Foundation of China [51804089]
- Science and Technology Base and Talent Project of Guangxi [GUIKEAD20159049]
- Guangxi Natural Science Foundation [2018GXNSFBA050056]
This review summarizes the recent advances in the controlled synthesis of hydroxide precursors and the growth of particles. The physical features of precursors significantly affect the electrochemical properties and battery performance of cathode materials. Innovative technologies for precursor modifications and novel precursor synthesis are highlighted. Future perspectives on the development of hydroxide precursors are presented.
The exploitation of clean energy promotes the exploration of next-generation lithium-ion batteries (LIBs) with high energy-density, long life, high safety, and low cost. Ni-rich layered cathode materials are one of the most promising candidates for next-generation LIBs. Numerous studies focusing on the synthesis and modifications of the layered cathode materials are published every year. Many physical features of precursors, such as density, morphology, size distribution, and microstructure of primary particles pass to the resulting cathode materials, thus significantly affecting their electrochemical properties and battery performance. This review focuses on the recent advances in the controlled synthesis of hydroxide precursors and the growth of particles. The essential parameters in controlled coprecipitation are discussed in detail. Some innovative technologies for precursor modifications and for the synthesis of novel precursors are highlighted. In addition, future perspectives of the development of hydroxide precursors are presented.
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