期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 291, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.seppur.2022.120924
关键词
Adsorbent; Lanthanum oxides; Cyanometallate; Phosphorus removal
资金
- Zhuhai Basic and Applied Basic Research Foundation [ZH22017003210025PWC]
- Advanced Institute of Natural Sciences, Beijing Normal University at Zhuhai
- National Natural Science Foundation of China [22006131]
This study synthesized a lanthanum-iron cyanometallate framework with rich hierarchical pores, and the resulting twin lotus flower oxide exhibited high-performance phosphate adsorption and excellent removal ability for stubborn low concentration phosphorus pollution.
Phosphorus (P) discharge is well recognized as the chief culprit of eutrophication and algal blooms. It is of pressing need to remove excessive phosphorus to protect the important watershed. Lanthanum (La) based materials are one type of attention-grabbing adsorbent due to their superior affinity to phosphate. Here, a La-Fe cyanometallate (CM) framework with a novel twin lotus flower structure was synthesized and rich hierarchical pores were fabricated via pyrolysis. The resultant twin lotus flower oxide of LaFe CM-500 was demonstrated to be a high-performance adsorbent for phosphate removal with a saturated capacity as high as 45.03 mg P/g. It also possessed superior removal ability for the stubborn low concentration of P pollution. The abundant hierarchical pores (from macropore to micropore) render a rapid diffusion of phosphate on the LaFe CM-500. The La components on porous adsorbent were verified to be the key active sites that form stable LaPO4 via a ligand exchange process. The effects of solution conditions (temperature, pH, co-existing ions, and humic acid) were also investigated, and a high selectivity for phosphate adsorption enables the as-prepared twin lotus flower adsorbent to be competitive in practical water body treatment.
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