4.7 Article

Room Temperature Deformation-induced Solute Segregation and its Impact on Twin Boundary Mobility in a Mg-Y Alloy

期刊

SCRIPTA MATERIALIA
卷 209, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2021.114375

关键词

Twinning; Basal-prismatic facet; Solute segregation; HAADF-STEM; Molecular dynamics

资金

  1. National Science Foundation (NSF) [CMMI-1729829, CMMI-1729887, CMMI-1723539]
  2. National Science Foundation Materials Research Science and Engineering Center program through the UC Irvine Center for Complex and Active Materials [DMR-2011967]

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The study investigates deformation-induced solute segregation in a Mg-Y alloy at room temperature. High concentrations of Y were observed at dislocation cores, and the segregation arrangement minimizes lattice distortion and is supported kinetically by dynamic interactions between solute atoms, crystallographic defects, and slip-twin interactions during plastic deformation.
Mechanical behavior of alloys is influenced by segregation of solute atoms, which affects deformation mechanisms, such as slip and twinning. In this study, we report on an atomic-scale investigation into room temperature, deformation-induced solute segregation in a Mg-Y alloy. High concentrations of Y were observed at the dislocation cores. In addition, we found that {10 (1) over bar2} twins were bounded by coher-ent twin boundaries and basal-prismatic facets, which contained periodic segregation of Y-rich columns and nano-sized Y-rich clusters, respectively. The observed segregation arrangement was energetically at-tributed to the fact that it minimizes the overall lattice distortion and is kinetically assisted by the dy-namic interaction between solute atoms and crystallographic defects and the slip-twin interaction during plastic deformation. Moreover, segregated Y atoms exert a pinning effect and lead to anisotropy on the mobility of twin boundaries. This finding offers a potentially new alloy design path to control the me-chanical response of Mg alloys. (C) 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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