期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 133, 期 26, 页码 -出版社
WILEY
DOI: 10.1002/app.43571
关键词
composites; mechanical properties; rubber
资金
- Special Fund for Agro-scientific Research in the Public Interest [201403066]
- Fundamental Scientific Research Funds for Chinese Academy of Tropical Agricultural Sciences [1630022014021]
- Natural Science Foundation of Hainan Province [512107]
Natural rubber-epoxidized natural rubber-silica composites were prepared by the wet masterbatch technique and the traditional dry mixing method. Performances of the composites based on different preparation methods were investigated with a moving die rheometer, an electronic universal testing machine, a dynamic mechanical analyzer, a nuclear magnetic resonance crosslink density analyzer, a rubber processing analyzer (RPA), a scanning electron microscope (SEM), and a transmission electron microscope (TEM). The RPA, SEM, and TEM analyses indicated that silica has better dispersion, lower filler-filler interaction, and better filler-rubber interaction in compounds based on the wet masterbatch technique, leading to improvements in mechanical strength and the dynamic mechanical and compression properties of the composites. It also indicates that composites prepared by the wet masterbatch technique have shorter scorch time, faster curing velocity, and higher crosslink density. The composites prepared by the wet materbatch technique also have lower rolling resistance, which is an important property for their use as a green material for the tire industry. (c) 2016 Wiley Periodicals, Inc.
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