期刊
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
卷 96, 期 3, 页码 478-484出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024422030244
关键词
thermodynamics; liquid-liquid; critical states
资金
- Russian Science Foundation [21-13-00038]
- Russian Science Foundation [21-13-00038] Funding Source: Russian Science Foundation
Thermodynamic relationships are used to analyze phase diagrams of systems with chemical interaction near critical points. New variables are introduced to represent mole fractions. A general equation is derived for the isothermal-isobaric curve of chemical equilibrium in generalized concentration variables. Analysis of chemically reacting liquid-liquid systems near critical points is conducted and corresponding diagrams are presented.
Thermodynamic relationships are obtained to analyze patterns in the phase diagrams of systems with chemical interaction between materials in the vicinity of critical points. The procedure is based on introducing new variables (analogs of mole fractions). A general equation is derived for the isothermal-isobaric curve of chemical equilibrium in generalized concentration variables. The behavior of chemically reacting liquid-liquid systems in the vicinity of the critical points of two-phase equilibria is analyzed, and the corresponding diagrams are presented.
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