4.1 Article

Modelling Electrocatalytic Reactions on Rotating Disk Electrodes

期刊

RUSSIAN JOURNAL OF ELECTROCHEMISTRY
卷 58, 期 3, 页码 202-209

出版社

PLEIADES PUBLISHING INC
DOI: 10.1134/S1023193522030077

关键词

rate constant of redox reaction; catalytic oxidation; kinetic current; simulation

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Kinetic currents resulting from the interaction between dissolved catalyst and substrate are calculated. The proposed method allows for testing the sigmoidal dependence of currents on the bulk concentration of catalyst and calculating the rate constant of the redox reaction. The applicability limits are discussed.
Kinetic currents caused by the interaction of dissolved catalyst and substrate are calculated. Sigmoidal dependence of currents on the bulk concentration of catalyst can be tested and the rate constant of redox reaction can be calculated by the proposed method. The applicability limits are discussed.

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