期刊
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
卷 48, 期 3, 页码 153-163出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/S107032842203006X
关键词
palladium; acetate complexes; ferrocenecarboxylic acid; synthesis; X-ray diffraction; crystal chemistry
资金
- Russian Science Foundation [18-73-10206]
- Russian Science Foundation [18-73-10206] Funding Source: Russian Science Foundation
In this study, a series of heterometallic palladium(II) complexes with ferrocenecarboxylic acid were synthesized and structurally characterized for the first time. The displacement of acetate anions by ferrocenecarboxylate anions during the synthesis process was observed.
Heterometallic palladium(II) complexes with ferrocenecarboxylic acid FcCOOH were synthesized and structurally characterized for the first time. The reactions of mononuclear [Pd(Py)(2)(OOCMe)(2)] and [Pd(Phen)(OOCMe)(2)] complexes with FcCOOH were accompanied by easy displacement of acetate anions from the inner sphere by the ferrocenecarboxylate anions to give iron-containing molecular palladium complexes: three solvatomorphs of [Pd(Py)(2)(FcCOO)(2)] with benzene (I, II) and dichloromethane (III); the use of [Pd(Phen)(OOCMe)(2)] as the starting compound resulted in the formation of the heteroligand acetate ferrocenecarboxylate [Pd(Phen)(FcCOO)(2)Pd(Phen)(FcCOO)(OOCMe)] (IV). Fully substituted [Pd(Phen)(FcCOO)(2)] (V) was prepared by successive treatment of palladium acetate [Pd-3(OOCMe)(6)] with FcCOOH and 1,10-phenanthroline. The structures of complexes I-V were studied by X-ray diffraction (CIF files CCDC nos. 2078399-2078403).
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