4.7 Article

Basic research on the microwave absorbing properties and microwave roasting kinetic of cyanide tailings

期刊

POWDER TECHNOLOGY
卷 401, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.powtec.2022.117346

关键词

Cyanide tailings; Dielectric properties; Gold; Microwave treatment; Kinetics study

资金

  1. Yunan Ten Thousand Talents Plan Young & Elite Talents Project [YNWR-QNBJ-2018-112]
  2. Opening Project of Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Ed-ucation [LYJ2001]
  3. Open Foundations of Sichuan Provincial Key Lab-oratory of Process Equipment and Control Engineering [GK201903, GK201916]

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This study explores the mechanism of microwave enhancement in the treatment of cyanide tailings using the microwave chlorination heat treatment process. The research finds that cyanide tailings have favorable microwave-absorbing performance and the heating efficiency and activation energy of gold chlorination reaction are significantly improved under the influence of iron oxide. The findings provide valuable references for the industrial application of microwave chlorination roasting on cyanide tailings.
In this study, a thorough exploration was performed on the mechanism of microwave enhancement in the treatment of cyanide tailings by the microwave chlorination heat treatment process. The improvement rate of the dielectric properties of tailing materials is rapid in the high temperature range (673-1173 K), which indicates that cyanide tailings have favorable microwave-absorbing performance. Under the action of iron oxide, the loss tangent of raw materials increased from 0.0364 to 0.1914. The heating efficiency improved significantly, from 6.73 K/min to 41.667 K/min. The kinetics experiment was performed on tailings in the two different roasting process. Compared with conventional roasting, the activation energy of the chlorination reaction of gold under the microwave roasting decreased by 32.47%. The work provides sound references for promoting the industrial application of microwave chlorination roasting on cyanide tailings. (c) 2022 Published by Elsevier B.V.

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