期刊
POLYMER DEGRADATION AND STABILITY
卷 200, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2022.109944
关键词
Polyester/cotton blend fabrics; Flame retardant; Antibacterial property; Hybrid coating
资金
- National Natural Science Foundation of China [51803007, 21875015]
- Key Laboratory of Flame Retardancy Finishing of Textile Materials, CNTAC [Q811580421]
In this study, an organic-inorganic hybrid coating was used to enhance the fire safety and antibacterial property of polyester/cotton blend fabrics. The hybrid coating was prepared through the in-situ growth of zirconium phosphate nanosheets and the formation of polyelectrolyte complex using phytic acid and poly(hexamethylene guanidine hydrochloride) via spraying method. The treated fabrics demonstrated self-extinguishing behavior in vertical burning test, increased LOI value and reduced heat release rate. The mechanical properties of the fabric were not significantly affected by the introduction of the coating. Additionally, the treated fabrics exhibited excellent antibacterial activity.
In this work, an organic-inorganic hybrid coating was used to improve the fire safety and antibacterial property of polyester/cotton blend fabrics. The hybrid coating was constructed by two steps, including the in-situ growth of zirconium phosphate nanosheets, and the preparation of polyelectrolyte complex with phytic acid and poly(hexamethylene guanidine hydrochloride) via spraying method. The flame retardancy and antibacterial activity of treated fabrics were completely investigated. A self-extinguishing behavior was observed in vertical burning test and the damaged length was only 5.4 cm. The LOI value of treated fabrics was increased from 19.0% of pristine fabrics to 27.8%, and the peak heat release rate and total heat release were decreased by 42% and 27%, respectively. Besides, thermogravimetric analysis revealed that the char residue increased from 8.3% to 26.3% at 800 degrees C, confirming a great char-forming ability of coated fabrics. Tensile strength test indicates that the introduction of coating had no seriously damage to the mechanical properties of fabric. Moreover, an excellent antibacterial property of treated fabrics was proved by using agar diffusion method. This research provides an environmentally friendly path for the flame retardant and antibacterial modification of polyester/cotton blend fabrics. (C) 2022 Elsevier Ltd. All rights reserved.
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