期刊
POLYMER
卷 252, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2022.124971
关键词
-
资金
- Walter P. Murphy Professorship
- U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy (EERE) under the Bioenergy Technologies Office Award [DE-EE0008928]
This study demonstrates the effectiveness of using POSS to enhance the reprocessable polyhydroxyurethane network composites, which exhibit improved storage modulus and creep resistance, and can undergo melt-state reprocessing at high temperature with 100% property recovery.
The rapid development of covalent adaptable networks or vitrimers shows promise for addressing the long-standing recycling issues associated with conventional, permanently cross-linked thermosets. At the same time, it is important to demonstrate that properties of reprocessable polymer networks can be optimized to meet the ongoing demand for high-performance materials. We have fabricated reprocessable polyhydroxyurethane (PHU) network composites reinforced with reactive polyhedral oligomeric silsesquioxanes (POSS). With functionalized POSS serving as a fraction of the cross-linkers, the PHU-POSS network nanocomposites exhibit significantly enhanced storage modulus at the rubbery plateau region relative to the neat PHU network. With up to 10 wt% POSS loading, these network composites can undergo melt-state reprocessing at 140 ? with 100% property recovery associated with cross-link density. We also show that hydroxyurethane dynamic chemistry leads to excellent creep resistance at elevated temperature up to 90 ? and is unaffected by reactive incorporation of POSS. This study demonstrates the effectiveness of POSS as nanofillers for designing high-performance, organic-inorganic dynamic PHU networks with excellent reprocessability.
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