期刊
POLYMER
卷 252, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2022.124963
关键词
Morphological regulation; Selective distribution; Electromagnetic shielding; Carbon nanotubes; PCL/PLA blends
资金
- National Natural Science Foundation of China [52173264]
- Natural Science Foundation Project of Chongqing [cstc2020jcyj-msxmX0401]
The migration behavior of carbon nanotubes and the mixing rates significantly affect the morphology and electromagnetic waves shielding performance of conductive polymer composites. Improved viscosity matching results in smaller phases size and enhanced microwave attenuation due to more interfaces.
Selective distribution of carbon nanotubes and morphology of conductive polymer composites were very important factors to their electrical conductivity and electromagnetic waves (EMW) shielding performance. Herein, the migration behavior of carbon nanotubes (CNTs) in co-continuous poly(lactic acid)/poly(e-caprolactone) (PLA/PCL) blend was investigated via pre-compounding CNTs in one phase and controlling the mixing time. Because of the higher interaction between CNTs and PCL phase, the migration of CNTs happened from PLA phase to PCL phase when CNTs were pre-mixed with PLA. Due to the viscosity enhancement of pre-compounding PCL/CNT and PLA/CNT, the matching viscosity-dependent morphology was obvious in the composites with different mixing sequences. The better viscosity matching of two polymer phases resulted in the smaller size of two phases, which had more interfaces to enhance microwave attenuation. The effect of CNTs migration and mixing rates on morphological size and EMW shielding performance of the composites were also evaluated. Specifically, the composites with pre-mixing PCL/CNT and then PLA at low shear stress exhibited the smaller size of phases and higher EMW shielding effectiveness (SE) values because of higher interfacial polarization and higher multiple reflection/scattering.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据