期刊
ORGANIC LETTERS
卷 24, 期 19, 页码 3461-3465出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c01034
关键词
-
资金
- National Science Foundation [CHE-1665208, CHE-2101153]
The assigned tetrasaccharide repeating subunit from the Acinetobacter baumannii KL4-associated capsular polysaccharide has been successfully synthesized through chemical synthetic efforts. A convergent synthetic strategy based on a 1,2-cis-selective [2+2] glycosylation was crucial for the synthesis of the fully protected tetrasaccharide.
Chemical synthetic efforts have resulted in the preparation of the assigned tetrasaccharide repeating subunit from the Acinetobacter baumannii KL4-associated capsular polysaccharide. A convergent synthetic strategy hinging on a 1,2-cis-selective [2+2] glycosylation to generate the fully protected tetrasaccharide was key to the success of this synthesis.
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