4.8 Article

Iridium(III)-Catalyzed Regioselective B(4)-H Allenylation of o-Carboranes by Ball Milling

期刊

ORGANIC LETTERS
卷 24, 期 17, 页码 3128-3133

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c00756

关键词

-

资金

  1. National Research Foundation of Korea (NRF) - Korean government [2021R1A2C3008862]
  2. National Research Foundation of Korea [2021R1A2C3008862] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

向作者/读者索取更多资源

This study presents a novel method for achieving regioselective B(4)-H allenylation of o-carboranes under ball-milling conditions, which cannot be achieved through conventional solution-based reactions.
We disclose an iridium(III)-catalyzed regioselective B(4)-H allenylation of o-carboranes from o-carborane acids and propargyl carbonates under ball-milling conditions. This study sheds light on a novel method to accomplish regioselective B(4)- allenylation of o-carborane that cannot be realized through conventional solution-based reactions. Control experiments, including solution, neat, microwave, and high-temperature reactions, reveal that the B(4)-H allenylation of o-carborane is unique for ballmilling conditions.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据