4.8 Article

Direct C-H Sulfonylimination of Pyridinium Salts

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ORGANIC LETTERS
卷 24, 期 15, 页码 2821-2825

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AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c00725

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  1. National Natural Science Foundation of China [21871187, 22072099]

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A direct and efficient synthesis method for sulfonyl iminopyridine derivatives has been developed, featuring the formation of a C-N bond with high functional group tolerance under metal-free conditions. The spectroscopic properties of these compounds have the potential to make them useful as new emitting materials.
A direct pyridinium C-H sulfonylimination has been developed for the synthesis of sulfonyl iminopyridinederivatives with high efficiency. This transformation features the direct and efficient formation of a C???N bond with a highfunctional group tolerance under metal-free conditions. The spectroscopic properties potentially enable these sulfonyl iminopyridinecompounds to be useful new emitting materials

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