期刊
ORGANIC LETTERS
卷 24, 期 10, 页码 1953-1957出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c00357
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资金
- Nanjing Tech University [39837118, 39837146]
- National Natural Science Foundation of China [22001121]
- Natural Science Foundation of Jiangsu Province [BK20180690]
- Nanjing Forestry University
The direct cross-couplings of aryl sulfonium salts with aryl halides using nickel as a reaction catalyst were successfully achieved. The reactions proceeded efficiently via C-S bond activation at ambient temperature, providing moderate to good yields, potentially serving as an attractive alternative to conventional cross-coupling reactions.
The direct cross-couplings of aryl sulfonium salts with aryl halides could be achieved by using nickel as a reaction catalyst. The reactions proceeded efficiently via C-S bond activation in the presence of magnesium turnings and lithium chloride in THF at ambient temperature to afford the corresponding biaryls in moderate to good yields, potentially serving as an attractive alternative to conventional cross-coupling reactions employing preprepared organometallic reagents.
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