Deoxygenative C-S Bond Coupling with Sulfinates via Nickel/Photoredox Dual Catalysis

The C-S bond formation from aryl halides and thiols has been well established under various catalytic systems. In this work, user-friendly sulfinates have been exploited as an efficient sulfenylating reagent in the C-S couplings through visible-light-induced photo/nickel dual catalysis under base- and external reductant-free conditions. A large number of aryl sulfide products were accessed with high selectivity and high tolerance of various functionalities.

Automated summary

In this study, sulfinates were successfully used as sulfenylating reagents in C-S couplings through visible-light-induced photo/nickel dual catalysis under base- and external reductant-free conditions. The method showed high selectivity and tolerance towards various functionalities.