期刊
NATURE MATERIALS
卷 21, 期 8, 页码 864-+出版社
NATURE PORTFOLIO
DOI: 10.1038/s41563-022-01262-w
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资金
- OMV Group
- Cambridge Trusts
- Winton Programme for the Physics of Sustainability, Cambridge Philosophical Society, Trinity College, St John's College
- EPSRC Department Training Partnership studentship [EP/N509620/1]
- Marie Sklodowska-Curie Individual European Fellowship (SolarFUEL) [GAN 839763]
- SNSF EPM Fellowship [P2BEP2_184483]
- Royal Academy of Engineering [RF\201718\1701]
- Royal Academy of Engineering Chair in Emerging Technologies scheme [CIET1819_24]
- Swiss National Science Foundation (SNF) [P2BEP2_184483] Funding Source: Swiss National Science Foundation (SNF)
In this study, photocathodes with long-lasting H2 evolution activity were demonstrated by integrating a BiOI light absorber into a robust, oxide-based architecture with a graphite paste conductive encapsulant. Multiple-pixel devices were introduced as an innovative design principle for PEC systems, showing superior photocurrents, onset biases, and stability compared to conventional single-pixel devices.
Photoelectrochemical (PEC) devices have been developed for direct solar fuel production but the limited stability of submerged light absorbers can hamper their commercial prospects.(1,2) Here, we demonstrate photocathodes with an operational H-2 evolution activity over weeks, by integrating a BiOI light absorber into a robust, oxide-based architecture with a graphite paste conductive encapsulant. In this case, the activity towards proton and CO2 reduction is mainly limited by catalyst degradation. We also introduce multiple-pixel devices as an innovative design principle for PEC systems, displaying superior photocurrents, onset biases and stability over corresponding conventional single-pixel devices. Accordingly, PEC tandem devices comprising multiple-pixel BiOI photocathodes and BiVO4 photoanodes can sustain bias-free water splitting for 240 h, while devices with a Cu92In8 alloy catalyst demonstrate unassisted syngas production from CO2.
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