Highly luminescent zero-dimensional lead-free manganese halides for β-ray scintillation

Because of their moderate penetration power, beta-rays (high-energy electrons) are a useful signal for evaluating the surface contamination of nuclear radiation. However, the development of beta-ray scintillators, which convert the absorbed high-energy electrons into visible photons, is hindered by the limitations of materials selection. Herein, we report two highly luminescent zero-dimensional (0D) organic-inorganic lead-free metal halide hybrids, (C13H30N)(2)MnBr4 and (C19H34N)(2)MnBr4, as scintillators exhibiting efficient beta-ray scintillation. These hybrid scintillators combine the superior properties of organic and inorganic components. For example, organic components that contain light elements C, H, and N enhance the capturing efficiency of beta particles; isolated inorganic [MnBr4](2-) tetrahedrons serve as highly localized emitting centers to emit intense radioluminescence (RL) under beta-ray excitation. Both hybrids show a narrow-band green emission peaked at 518 nm with photoluminescence quantum efficiencies (PLQEs) of 81.3% for (C13H30N)(2)MnBr4 and 86.4% for (C19H34N)(2)MnBr4, respectively. To enable the solution processing of this promising metal halide hybrid, we successfully synthesized (C13H30N)(2)MnBr4 colloidal nanocrystals for the first time. Being excited by beta-rays, (C13H30N)(2)MnBr4 scintillators show a linear response to beta-ray dose rate over a broad range from 400 to 2,800 Gy.s(-1), and also display robust radiation resistance that 80% of the initial RL intensity can be maintained after an ultrahigh accumulated radiation dose of 240 kGy. This work will open up a new route for the development of beta-ray scintillators.

Automated summary

In this study, we report two highly luminescent zero-dimensional organic-inorganic lead-free metal halide hybrids as efficient beta-ray scintillators. These hybrid scintillators combine the superior properties of organic and inorganic components, exhibiting high luminescence efficiency and linear response to beta-ray dose rate, as well as robust radiation resistance.