期刊
MOLECULES
卷 27, 期 9, 页码 -出版社
MDPI
DOI: 10.3390/molecules27093007
关键词
crystallization; nucleation; interfacial energy; induction time; metastable zone width
资金
- Ministry of Science and Technology of Taiwan [MOST110-2221-E-182-006-MY2]
- Chang Gung Memorial Hospital [CMRPD2K0012]
A linearized integral model is used in this study to determine the interfacial energy and pre-exponential factor. The results show that the calculated values from different methods are consistent for the studied systems.
A linearized integral model based on classical nucleation theory is applied in this work to determine the interfacial energy and pre-exponential factor using a linear plot from the cumulative distributions of the metastable zone width (MSZW) data for some systems reported in the literature, including isonicotinamide, butyl paraben, dicyandiamide, and salicylic acid. Based on the same criterion for the nucleation point, the interfacial energy and pre-exponential factor are determined using the conventional linear regression method from the cumulative distributions of the induction time data for the same systems. The results indicate that the interfacial energy and pre-exponential factor calculated from the MSZW data are consistent with those calculated from the induction time for the studied systems.
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