期刊
MENDELEEV COMMUNICATIONS
卷 32, 期 3, 页码 367-370出版社
ELSEVIER
DOI: 10.1016/j.mencom.2022.05.025
关键词
naphthothiophenes; crown ethers; complex formation; redox properties; absorption; fluorescence; barium complexes; magnesium complexes; spectroelectrochemistry
资金
- Russian Science Foundation [17-73-30036]
New polycyclic aromatic derivatives, crown naphthothiophenes, annulated both with thiophene and with 15-crown-5 ether moieties, were successfully synthesized via the Mallory photocyclization. Their complexation with Ba2+ and Mg2+ cations was investigated using optical and electrochemical methods, revealing the chemical stability of the compounds in the oxidized state depending on their structure.
New polycyclic aromatic derivatives annulated both with thiophene and with 15-crown-5 ether moieties, crown naphthothiophenes, were synthesized via the Mallory photocyclization with the use of iodine as the mild oxidizer, while two isomeric products were readily separated by column chromatography. Their complexation with Ba2+ and Mg2+ cations was examined by both optical and electrochemical methods. Spectroelectrochemical studies indicate that the obtained compounds, depending on their structure, can be chemically stable in the oxidized state.
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