期刊
MENDELEEV COMMUNICATIONS
卷 32, 期 2, 页码 170-172出版社
ELSEVIER
DOI: 10.1016/j.mencom.2022.03.005
关键词
Keywords; donor-acceptor cyclopropanes; gallium salts; (thiophen-2-yl)cyclopropane dicarboxylate; ipso -dimerization; pentaleno[6a; b ]
A selectivity-switched dimerization process was developed using anhydrous Gaiii salts as catalysts, resulting in selective formation of two different derivatives. The crucial role of a phenyl substituent at position 5 of the thiophene ring and some regularities were investigated.
A selectivity-switched dimerization process for (5-phenyl-2thienyl)cyclopropane-1,1-dicarboxylate under activation conditions with anhydrous Gaiii salts was developed. Using GaCl3 or Ga(NTf2)3 as catalysts, 3a,4,5a,6,7,8-hexahydro5H-pentaleno[6a,1-b]thiophene and 5,6-dihydro-4H-cyclopenta[b]thiophene derivatives can be selectively obtained as a result of ipso-type and [3+2]-annulation type dimerization. The crucial role of a phenyl substituent at position 5 of the thiophene ring and some regularities are discussed.
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