4.8 Review

A comprehensive review of template-assisted porous carbons: Modern preparation methods and advanced applications

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Review Environmental Sciences

Preparation and Application of Hierarchical Porous Carbon Materials from Waste and Biomass: A Review

Xiao-Li Zhou et al.

Summary: Hierarchical porous carbon materials with organized pores of different scales exhibit high performance in various applications due to the functional combination of hierarchical pores. This paper reviews the preparation of HPC from waste and biomass, as well as their potential applications, discussing the influences of activating agents and conditions on the specific surface area and pore volume. Novel technologies for preparing HPC from non-structured raw materials and advanced applications in energy storage, deionization, adsorption and catalysis are also summarized.

WASTE AND BIOMASS VALORIZATION (2021)

Article Energy & Fuels

Salt-recrystallizationpreparation of metal organic framework derived porous carbon support forhighly-efficientproton exchange membrane fuel cell

Mengjun Wu et al.

Summary: A novel carbon support material (C-framework) for PEMFC was reported using salt-recrystallization-fixing HKUST-1 template. The C-framework loaded with Pt nanoparticles exhibited high ORR activity and excellent electrochemical performance in acidic electrolytes. The PEMFC performance reached a maximum power density of 780 mW/cm(2) under ultra-low Pt loading.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2021)

Article Chemistry, Physical

Nitrogen-phosphorus co-doped porous carbon using ionic liquids as a dual functional agent for high-performance long-life lithium ion batteries

Ying-xue Guo et al.

Summary: A new nitrogen-phosphorus co-doped porous carbon material with uniform porous structure and high specific surface area was synthesized using ionic liquids and salt templates. This material exhibited excellent electrochemical properties as an anode material for lithium-ion batteries, with high initial discharge capacity, good cycling stability, and high coulombic efficiency, making it a promising candidate for battery applications.

IONICS (2021)

Article Green & Sustainable Science & Technology

Facile synthesis of sludge-based mesoporous carbon with flocculants: Effect of template on the synthetic behavior and improved phenol capture

Wang Xin et al.

Summary: Based on the self-assembly of materials and pyrolysis technology, a template-like method was developed to construct sewage sludge-based mesoporous carbons (SSMCs) by employing different flocculants as templates. The method enhances the surface properties and adsorption performance of SSMCs, offering a new perspective for the utilization of excess sludge in sewage treatment plants.

JOURNAL OF CLEANER PRODUCTION (2021)

Article Chemistry, Physical

Co/nitrogen-doped carbon nanocomposite derived from self-assembled metallogels as efficient bifunctional oxygen electrocatalyst for Zn-air batteries

Ningzhao Shang et al.

Summary: The folic acid based metal-organic gels synthesized through coordination induced self-assemble strategy show good dispersion and larger accessible surface areas, providing potential to enhance the oxygen reduction reaction and oxygen evolution reaction activities in nonprecious metal based bifunctional electrocatalysts for metal-air batteries.

APPLIED SURFACE SCIENCE (2021)

Article Chemistry, Physical

Molten salt template-assisted synthesis of N, S-codoped hierarchically porous carbon nanosheets for efficient energy storage

Huadong Tian et al.

Summary: In this study, N/S co-doped hierarchical porous carbons were prepared using a novel method and exhibited excellent electrochemical performance in double-layer supercapacitors. The obtained carbons showed well-developed structure and composition, facilitating charge transport and exposure of surface active sites.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

Article Chemistry, Physical

Tuning the Nanoporous Structure of Carbons Derived from the Composite of Cross-Linked Polymers for Charge Storage Applications

Farshad Barzegar et al.

Summary: Controlling the porosity of carbon-based electrodes is crucial for enhancing the performance of charge storage devices such as supercapacitors. This study demonstrates an eco-friendly method for preparing carbon materials with optimized pore structures, leading to improved surface characteristics and interconnected porous structure suitable for ionic transport. The composite materials show stable capacitance and energy efficiency, making them promising for use in supercapacitors.

ACS APPLIED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Porosity and composition of nitrogen-doped carbon materials templated by the thermolysis products of calcium tartrate and their performance in electrochemical capacitors

Alina D. Nishchakova et al.

Summary: Porous nitrogen-doped carbon materials were synthesized using template nanoparticles produced by the decomposition of calcium tartrate in thermal shock conditions. Increasing the synthesis temperature led to more ordered graphitic layers but decreased specific surface area and total pore volume. The material synthesized at 750 degrees Celsius showed the best electrochemical performance due to the presence of pyridinic nitrogen, graphitic nitrogen, and large-size mesopores.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Facile preparation of Ni nanoparticle embedded on mesoporous carbon nanorods for non-enzymatic glucose detection

Huixian Jia et al.

Summary: This study developed a simple strategy to construct Ni/NCNs, which exhibited remarkable performance as a glucose sensor. The sensor showed ultra-low detection limit, wide linear detection ranges, fast response times, and good stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Applied

Synthesis of large pore sized mesoporous carbon using alumina-templated strategy for high-performance RhB removal

Xuhui Wang et al.

Summary: Mesoporous carbon materials synthesized through alumina-templated strategy exhibit large BET surface area, pore volume, and pore size, leading to high adsorption capacity for RhB. The kinetics module fits pseudo-second-order kinetic model and Langmuir model, showing potential for toxic dye wastewater treatments.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

Article Environmental Sciences

Modification of structured bio-carbon derived from spongin-based scaffolds with nickel compounds to produce a functional catalyst for reduction and oxidation reactions: Potential for use in environmental protection

Sonia Zoltowska et al.

Summary: Three different 3D fibrous-like NiO/Ni(OH)(2)/Ni-carbonized spongin-based materials were prepared using a sorption-reduction method, showing promising catalytic activity in oxidation and reduction reactions. The oxidation efficiency varied depending on the substrate, with superior activity observed in reduction reactions. The catalysts also exhibited good reusability and kinetic properties.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

Review Chemistry, Physical

Synthesis strategies of templated porous carbons beyond the silica nanocasting technique

Noel Diez et al.

Summary: The review discusses the importance of porous carbons in environmental remediation and emerging energy applications. It highlights sustainable templating strategies using easily removable inorganic particles or polymeric materials. The fundamental aspects, advances, applications, and challenges of producing porous carbons with various morphologies and pore structures are analyzed in detail.

CARBON (2021)

Review Materials Science, Multidisciplinary

Graphitic carbon nitride-based materials for photocatalytic antibacterial application

Xinyue Kong et al.

Summary: This review summarizes the basic characteristics, preparation methods, and photocatalytic antibacterial mechanism of metal-free polymeric two-dimensional nanomaterial graphitic carbon nitride (g-C3N4), emphasizing the importance of increasing light utilization, reducing recombination of electron-hole pairs, and maintaining biocompatibility and environmental friendliness. Furthermore, various modification strategies and examples of combining g-C3N4's photocatalytic antibacterial effect with other strategies to achieve synergistic effects are introduced.

MATERIALS SCIENCE & ENGINEERING R-REPORTS (2021)

Article Engineering, Environmental

Three-dimensional commercial-sponge-derived Co3O4@C catalysts for effective treatments of organic contaminants

Sonia Zoltowska et al.

Summary: This study utilized spongin-based scaffolds of commercial sponge origin for the preparation of novel catalysts through simple functionalization with cobalt, showing good activity and reusability in oxidation-reduction reactions. The materials prepared demonstrated a fibrous structure with open porous canals, allowing for good accessibility of substrates to the catalyst surfaces. The adaptability of spongin-based scaffolds in preparing biocarbons with high potential for various catalytic applications was proven.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

Article Materials Science, Multidisciplinary

Synthesis of hierarchical zeolite templated carbons

T. Aumond et al.

Summary: The achievement of hierarchical zeolite templated carbons (ZTCs) utilizing mesoporous zeolites as sacrificial scaffolds was reported. The obtained hierarchical ZTCs feature tailored microporosity and high mesoporosity, bridging the gap between classical ZTCs and CMK-like materials. The rearrangement of surfactant-templated mesoporosity during ZTC formation impacts the crystal size and lattice strain of the zeolite template, while the surfactant-templating of USY zeolite leads to the development of a secondary amorphous phase.

CARBON TRENDS (2021)

Article Chemistry, Multidisciplinary

Hierarchically porous carbon cages synthesized through in situ migration of templates

Qing Fang et al.

CHINESE CHEMICAL LETTERS (2020)

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Enhanced current production of the anode modified by microalgae derived nitrogen-rich biocarbon for microbial fuel cells

Linghan Lan et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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A controllable soft-templating approach to synthesize mesoporous carbon microspheres derived from D-xylose via hydrothermal method

Jian Su et al.

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Characterization of Chicken Feather Biocarbon for Use in Sustainable Biocomposites

Zonglin Li et al.

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Construction of oxidized millimeter-sized hierarchically porous carbon spheres for U(VI) adsorption

Zhimin Dong et al.

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Jingen Xi et al.

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Biomass-Derived Carbon for Electrode Fabrication in Microbial Fuel Cells: A Review

Wei Yang et al.

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DFT study of hydrogen storage on the metallic decoration of boron substitution on zeolite templated carbon vacancy

Frank J. Isidro-Ortega et al.

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Mi Wang et al.

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Thayara Ceregatti et al.

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Seaweed-derived KOH activated biocarbon for electrocatalytic oxygen reduction and supercapacitor applications

K. Y. Perez-Salcedo et al.

JOURNAL OF POROUS MATERIALS (2020)

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Porous Self-Assembled Molecular Networks as Templates for Chiral-Position-Controlled Chemical Functionalization of Graphitic Surfaces

Kazukuni Tahara et al.

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Ana Claudia Fingolo et al.

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Covalent Functionalization of Carbon Surfaces: Diaryliodonium versus Aryldiazonium Chemistry

Roelof Steeno et al.

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Effect of SWCNT Content and Water Vapor Adsorption on the Electrical Properties of Cellulose Nanocrystal-Based Nanohybrids

Ainhoa Angulo Dehesa et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Article Chemistry, Applied

Nanoporous carbon hybrids derived from polymethylsilsequioxane for ultracapacitor electrodes

Ipsita P. Swain et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2020)

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Hollow carbon microbox from acetylacetone as anode material for sodium-ion batteries

Tianyun Qiu et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

Article Engineering, Environmental

Ash removal from various spent liquors by oxidation process for bio-carbon production

Zainab Al-Kaabi et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2020)

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Precise carbon structure control by salt template for high performance sodium-ion storage

Dong Qiu et al.

JOURNAL OF ENERGY CHEMISTRY (2019)

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Facile synthesis of nitrogen-enriched nanoporous carbon materials for high performance supercapacitors

Dandan Guo et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Block copolymer-based porous carbon fibers

Zhengping Zhou et al.

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Zeolite-Templated Carbon as the Cathode for a High Energy Density Dual-Ion Battery

Romain J. -C. Dubey et al.

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Development of enterosorbents that can be added to food and water to reduce toxin exposures during disasters

Meichen Wang et al.

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Impact of Fe deposition on microwave absorption properties of ordered mesoporous carbon flakes

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Fabrication of Nanoporous Carbon Materials with Hard- and Soft-Templating Approaches: A Review

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JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY (2019)

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General Synthesis Approach for Hierarchically Porous Materials via Reverse Microemulsion System

Xiaojian Hou et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Experimental and DFT study on the adsorption of VOCs on activated carbon/metal oxides composites

Ke Zhou et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Rheological investigation of carbon-based hybrid polyurethane nanocomposites with continuous networks

Iman Sahebi Jouibari et al.

IRANIAN POLYMER JOURNAL (2019)

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Attachment of redox active molecules on the carbon additive and its effect on the cycling performance of LiFePO4 electrodes

Hamidreza Saneifar et al.

MATERIALS CHEMISTRY AND PHYSICS (2019)

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Aerosol-Jet-Printed Preferentially Aligned Carbon Nanotube Twin-Lines for Printed Electronics

Guo Liang Goh et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Ordered Nanoporous Carbons with Broadly Tunable Pore Size Using Bottlebrush Block Copolymer Templates

Hua-Feng Fei et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Co/Co3O4 Nanoparticles Coupled with Hollow Nanoporous Carbon Polyhedrons for the Enhanced Electrochemical Sensing of Acetaminophen

Kaidong Wang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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MOF derived porous carbon modified rGO for simultaneous determination of hydroquinone and catechol

Han Chen et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2019)

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Ordered micro-mesoporous carbon from palm oil cooking waste via nanocasting in HZSM-5/SBA-15 composite: Preparation and adsorption studies

Raimundo Alves Lima Sobrinho et al.

JOURNAL OF HAZARDOUS MATERIALS (2019)

Article Chemistry, Applied

Fabrication of ordered mesoporous carbons with tunable pore architecture by the cosolvent

Peng Li et al.

JOURNAL OF POROUS MATERIALS (2019)

Article Chemistry, Applied

Nitrogen-doped hierarchical porous carbon for supercapacitors with high rate performance

Le Wang et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2019)

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One-pot synthesis of unique skin-tissue-bone structured porous carbons for enhanced supercapacitor performance

Dong Yan et al.

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Double-slit photoelectron interference in strong-field ionization of the neon dimer

Maksim Kunitski et al.

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Occurrence of the potent mutagens 2-nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles

Aldenor G. Santos et al.

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Ordered Mesoporous Graphitic Carbon/Iron Carbide Composites with High Porosity as a Sulfur Host for Li-S Batteries

Hao Wei et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Chemistry, Multidisciplinary

Ordered mesoporous carbons from lignin: a new class of biobased electrodes for supercapacitors

Servann Herou et al.

GREEN CHEMISTRY (2019)

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Bicontinuous Electrolytes via Thermally Initiated Polymerization for Structural Lithium Ion Batteries

Lynn M. Schneider et al.

ACS APPLIED ENERGY MATERIALS (2019)

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Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes: a review

Zhihong Bi et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Multidisciplinary

A preceramic polymer derived nanoporous carbon hybrid for supercapacitors

Ipsita P. Swain et al.

CHEMICAL COMMUNICATIONS (2019)

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Cobalt Nanoparticles Chemically Bonded to Porous Carbon Nanosheets: A Stable High-Capacity Anode for Fast-Charging Lithium-Ion Batteries

Vinodkumar Etacheri et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Nanoscience & Nanotechnology

MOF-Templated Fabrication of Hollow Co4N@N-Doped Carbon Porous Nanocages with Superior Catalytic Activity

Jianping Sheng et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Review Chemistry, Multidisciplinary

Recent advances in functionalized micro and mesoporous carbon materials: synthesis and applications

Mercy R. Benzigar et al.

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Review Chemistry, Medicinal

Marine Spongin: Naturally Prefabricated 3D Scaffold-Based Biomaterial

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N-Doped Porous Carbon Nanofibers/Porous Silver Network Hybrid for High-Rate Supercapacitor Electrode

Qingshi Meng et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Highly Ordered Nitrogen-Rich Mesoporous Carbon Nitrides and Their Superior Performance for Sensing and Photocatalytic Hydrogen Generation

Gurudas P. Mane et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Physical

Templated mesoporous carbons: Synthesis and applications

Michio Inagaki et al.

CARBON (2016)

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Opening of Bottleneck Pores for the Improvement of Nitrogen Doped Carbon Electrocatalysts

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2D MATERIALS (2016)

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Marine sponge skeleton photosensitized by copper phthalocyanine: A catalyst for Rhodamine B degradation

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OPEN CHEMISTRY (2016)

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Activated-Carbon-Templated Crystalline Tantalates for Photocatalytic Water Splitting

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CHEMNANOMAT (2016)

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Ultrastructural Characterization of the Lower Motor System in a Mouse Model of Krabbe Disease

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SCIENTIFIC REPORTS (2016)

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Synthesis of hollow carbon nanostructures using a ZnO template method

Liu Hong-yang et al.

NEW CARBON MATERIALS (2016)

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Large-scale synthesis of high-quality zeolite-templated carbons without depositing external carbon layers

Seokin Choi et al.

CHEMICAL ENGINEERING JOURNAL (2015)

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Development of Biochar-Based Functional Materials: Toward a Sustainable Platform Carbon Material

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CHEMICAL REVIEWS (2015)

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Soft and hard templating of graphitic carbon nitride

Zhao Yang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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MOF-derived Nanoporous Carbon as Intracellular Drug Delivery Carriers

Nagy L. Torad et al.

CHEMISTRY LETTERS (2014)

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Functionalized Carbon Nanoparticles, Blacks and Soots as Electron- Transfer Building Blocks and Conduits

Katherine Lawrence et al.

CHEMISTRY-AN ASIAN JOURNAL (2014)

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ZIF-derived in situ nitrogen-doped porous carbons as efficient metal-free electrocatalysts for oxygen reduction reaction

Peng Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Synthesis of high surface area silica gel templated carbon for hydrogen storage application

Ruhit Jyoti Konwar et al.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2014)

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Hierarchical porous carbons by liquid phase impregnation of zeolite templates with lignin solution

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MICROPOROUS AND MESOPOROUS MATERIALS (2014)

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Photocatalytic performance of TiO2-zeolite templated carbon composites in organic contaminant degradation

Waleeporn Donphai et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

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The Elemental Composition of Demospongiae from the Red Sea, Gulf of Aqaba

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PLOS ONE (2014)

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Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons

Rahul R. Salunkhe et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Amorphous water in three-dimensional confinement of zeolite-templated carbon

Haruka Kyakuno et al.

CHEMICAL PHYSICS LETTERS (2013)

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Carbon nanotube based electrochemical sensor for the sensitive detection of valacyclovir

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FARADAY DISCUSSIONS (2013)

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Preparation of ultrahigh surface area porous carbons templated using zeolite 13X for enhanced hydrogen storage

Eric Masika et al.

PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL (2013)

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A perspective on carbon materials for future energy application

Dang Sheng Su et al.

JOURNAL OF ENERGY CHEMISTRY (2013)

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Functionalization of porous carbons for catalytic applications

Jose Luis Figueiredo

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Templated Nanocarbons for Energy Storage

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ADVANCED MATERIALS (2012)

Article Chemistry, Multidisciplinary

Bacteria promoted hierarchical carbon materials for high-performance supercapacitor

Hongmei Sun et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

Article Chemistry, Physical

Role of silica template in the preparation of sulfonated mesoporous carbon catalysts

Jidon Janaun et al.

APPLIED CATALYSIS A-GENERAL (2011)

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Drug-Delivery Strategies by Using Template-Synthesized Nanotubes

Jillian L. Perry et al.

CHEMISTRY-A EUROPEAN JOURNAL (2011)

Article Materials Science, Multidisciplinary

Hard-templating synthesis of mesoporous carbon spheres with controlled particle size and mesoporous structure for enzyme immobilization

Jitong Wang et al.

MATERIALS CHEMISTRY AND PHYSICS (2011)

Review Chemistry, Multidisciplinary

Morphology and pore control in carbon materials via templating

M. Inagaki et al.

RSC ADVANCES (2011)

Article Chemistry, Physical

Porous graphitic carbon sorbents in biomedical and environmental applications

Monika Michel et al.

ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY (2009)

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Highly Efficient Adsorption of Bulky Dye Molecules in Wastewater on Ordered Mesoporous Carbons

Xin Zhuang et al.

CHEMISTRY OF MATERIALS (2009)

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Zeolite-Templated Microporous Carbon As a Superior Adsorbent for Removal of Monoaromatic Compounds from Aqueous Solution

Liangliang Ji et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2009)

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Controlled synthesis of core/shell magnetic iron oxide/carbon systems via a self-template method

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JOURNAL OF MATERIALS CHEMISTRY (2009)

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Preparation and application of mesoporous Fe/carbon composites as a drug carrier

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MICROPOROUS AND MESOPOROUS MATERIALS (2009)

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Synthesis of porous carbon fibers from collagen fiber

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CHEMSUSCHEM (2008)

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Adsorption of cationic dye from aqueous solutions by activated carbon

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MICROPOROUS AND MESOPOROUS MATERIALS (2008)

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Carboxy-mesoporous carbon and its excellent adsorption capability for proteins

Ajayan Vinu et al.

JOURNAL OF MATERIALS CHEMISTRY (2007)

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Takashi Kyotani

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2006)

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NANOMEDICINE (2006)

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Adsorption of cytochrome c on new mesoporous carbon molecular sieves

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Fabrication of ordered uniform porous carbon networks and their application to a catalyst supporter

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