4.6 Article

Improved performance of transparent p-type conductors CuCrO2:Mg delafossite thin films through easy and low cost laser annealing

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MATERIALS LETTERS
卷 313, 期 -, 页码 -

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DOI: 10.1016/j.matlet.2022.131795

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Delafossite; Laser direct writing; p-Type transparent conductors oxide (TCO)

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Laser annealing by a photolithography machine is interesting for enhancing the p-type transparent conductor properties of delafossite phases, and the prospect of local annealing according to selected patterns opens up exciting possibilities for fast and low-cost manufacturing of these transparent p-type semiconductors.
Films deposited on glass substrate by RF sputtering, were heat treated in air by a low power laser spot thanks to conventional photolithography machine, to obtain pure CuCr0.97Mg0.03O2 delafossite with an optical transmittance of 0.58 and a conductivity of 5.8S.cm(-1). The Haacke's figure of merit is improved to reach 2.07 x 10(7)Omega(-1). Laser annealing by a photolithography machine is thus very interesting for enhancing the p-type transparent conductor properties of such delafossite phases. A local annealing according to selected patterns could also be envisaged, opening up exciting prospects for fast and low cost making the most of these transparent ptype semiconductors.

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