期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 283, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2022.126013
关键词
Cermet composite; Metal foam; Microstructure; Thermal conductivity; Catalytic activity
资金
- Belarusian Republican Foundation for Fundamental Research [T20R-049]
- Russian Foundation for Basic Research [20-53-00009-Bel]
Metal foam reinforced cermet-matrix composites were synthesized using a low-temperature hydrothermal treatment, showing improved compressive strength and bi-porous structure. The metal foam skeleton increased thermal conductivity and prevented catastrophic destruction. The copper foam reinforced cermet catalyst exhibited higher activity in catalytic reactions.
Metal foam reinforced FeAlOy/FeAlx cermet-matrix composites for catalytic applications were synthesized by a low-temperature hydrothermal treatment of preforms consisting of an open-cell metal foam skeleton and a mechanically alloyed Fe-Al powder filling the metal foam cells. The composites had a compressive strength of about 100 MPa and a well-developed bi-porous structure. The metal foam skeleton in the composites ensured the increased thermal conductivity that was up to three times higher compared to non-reinforced cermet. In addition, the metal foam skeleton prevented catastrophic destruction at critical mechanical stresses. Comparative studies of the non-reinforced and copper foam reinforced cermet catalysts in the water-gas shift reaction revealed higher activity of the latter, which could be attributed to higher thermal conductivity and more favorable porous structure.
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