期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 282, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2022.125971
关键词
Organic photovoltaic cells; Halogen solvents; Non-halogen solvents; PCE
资金
- Ministry of Science and Technology, Taiwan [MOST 110-2622-E-131-006]
This paper describes high-performance PM6:BTP-eC9-based organic photovoltaic (OPV) cells prepared using non-halogen solvents. Three green solvents were investigated as replacements for chloroform. The optoelectronic properties of the blend films and their respective devices were optimized and analyzed. The OPV cell prepared with toluene as the solvent and 1,8-diiodooctane (DIO) as the additive showed the best performance.
In this paper we describe high-performance PM6:BTP-eC9-based organic photovoltaic (OPV) cells prepared using non-halogen solvents, with the goal of minimizing any potential environmental pollution. We investigated three green solvents (toluene, o-xylene, and 1,2,4-trimethylbenzene) as replacements for the commonly used chloroform. Using UV-Vis spectroscopy, atomic force microscopy, two-dimensional grazing incidence wide-angle X-ray spectroscopy, and carrier transport analysis, we optimized the blend films and investigated their optoelectronic properties and those of their respective devices. Among our tested devices, the OPV cell prepared with toluene as the solvent and 1,8-diiodooctane (DIO) as the additive displayed the best performance, with a power conversion efficiency (15.8 +/- 0.20%) comparable with that of the chloroform-derived OPV (16.2 +/- 0.1%). Thus, it is feasible to replace halogen solvents with non-halogen solvents when preparing OPV devices.
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