期刊
MACROMOLECULAR MATERIALS AND ENGINEERING
卷 307, 期 7, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.202100893
关键词
carbon fibers recycling; composites; degradable polymers; vanillin; vitrimers
资金
- Natural Science Foundation of Hubei Province [2020CFB412, 2019CFB346]
This study investigates the recycling of carbon fiber using bio-based polyimine vitrimers. The results show that the polyimine vitrimers exhibit good mechanical and degradation properties, and can effectively recycle carbon fiber under mild conditions. This research is significant for the development of eco-friendly carbon fiber composites.
Both environmental and economic factors have driven the development of degradable resin for carbon fiber (CF) recycling under mild conditions. However, the vast majority of thermosetting materials are difficult to recycle. This paper presents bio-based polyimine vitrimers to fully recycle the CF. The effect of vitrimers fine structures on the thermal, mechanical, solvent resistance, and degradation properties is carefully investigated. The tensile strength at break and Young's Modulus of pure polyimine vitrimers reach approximate to 80.3 MPa and 2.89 GPa. Importantly, the mechanical property of isophoronediamine-based polyimine vitrimers/two-layers CF exhibits a slightly inferior value to that of bisphenol A epoxy. Polyimine vitrimers are easily degradable under acid solution at 60 degrees C for 24 h. The surface morphology and chemical structure of CF are not changed after recycling. This work on mildly degradable polyimine vitrimers from vanillin and readily recycling of CF is desirable for the development of eco-friendly CF composites and lignin functional materials.
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