期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 144, 期 20, 页码 8902-8907出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.2c02922
关键词
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资金
- NIH [GM114547]
- National Research Foundation of Korea (NRF) for a postdoctor a l fellowship [2021R1A6A3A03044649]
- National Research Foundation of Korea [2021R1A6A3A03044649] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The study presents a catalytic approach to chemoselective primary amination of arylboronic acids, demonstrating an efficient synthesis strategy for versatile primary arylamines.
A catalytic approach to intercept the transient HNO for a chemoselective primary amination of arylboronic acids isreported. A phosphetane-based catalyst operating within PIII/PV???O redox cycling is shown to capture HNO, generated in situ byNef decomposition of 2-nitropropane, to selectively install the primary amino group at aryl Csp2centers. The method furnishesversatile primary arylamines from arylboronic acid substrates with the preservation of otherwise reactive functional groups
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