期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 144, 期 19, 页码 8658-8668出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.2c01503
关键词
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资金
- National Natural Science Foundation of China [51922074, 22075194, 51820105003]
- National Key Research and Development Program of China [2020YFB1506400]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [20KJA430010]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Collaborative Innovation Center of Suzhou Nano Science and Technology
- National Postdoctoral Program for Innovative Talents [BX2021205]
In this study, an ionic liquid (IL)-type reducing agent containing Cl- and a dihydroxyl group was used to control the reduction process of silver (Ag) in AgNW-based FTEs, achieving atomic-level contact between AgNWs and reduced Ag, thus improving the mechanical stability and optoelectronic properties of flexible FTEs.
Solution processable flexible transparent electrodes (FTEs) are urgently needed to boost the efficiency and mechanical stability of flexible organic solar cells (OSCs) on a large scale. However, how to balance the optoelectronic properties and meanwhile achieve robust mechanical behavior of FTEs is still a huge challenge. Silver nanowire (AgNW) electrodes, exhibiting easily tuned optoelectronic/mechanical properties, are attracting considerable attention, but their poor contacts at the junction site of the AgNWs increase the sheet resistance and reduce mechanical stability. In this study, an ionic liquid (IL)-type reducing agent containing Cl- and a dihydroxyl group was employed to control the reduction process of silver (Ag) in AgNW-based FTEs precisely. The Cl- in the IL regulates the Ag+ concentration through the formation and dissolution of AgCl, whereas the dihydroxyl group slowly reduces the released Ag+ to form metal Ag. The reduced Ag grew in situ at the junction site of the AgNWs in a twin-crystal growth mode, facilitating an atomic-level contact between the AgNWs and the reduced Ag. This enforced atomic-level contact decreased the sheet resistance, and enhanced the mechanical stability of the FTEs. As a result, the single-junction flexible OSCs based on this chemically welded FTE achieved record power conversion efficiencies of 17.52% (active area: 0.062 cm(2)) and 15.82% (active area: 1.0 cm(2)). These flexible devices also displayed robust bending and peeling durability even under extreme test conditions.
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