期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 144, 期 12, 页码 5450-5460出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.1c13295
关键词
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资金
- European Research Council (ERC) [279548]
- MICINN [CTQ2017-84727-P, RED2018-102331-T, PID2020-116921GB-I00]
Self-sorting phenomena play a crucial role in various (bio)chemical processes, and the chelate cooperativity is identified as a key factor in achieving high self-sorting fidelities.
Self-sorting phenomena are the basis of manifold relevant (bio)chemical processes where a set of molecules is able to interact with no interference from other sets and are ruled by a number of codes that are programmed in molecular structures. In this work, we study, the relevance of chelate cooperativity as a code for achieving high self-sorting fidelities. In particular, we establish qualitative and quantitative relationships between the cooperativity of a cyclic system and the self-sorting fidelity when combined with other molecules that share identical geometry and/or binding interactions. We demonstrate that only systems displaying sufficiently strong chelate cooperativity can achieve quantitative narcissistic self-sorting fidelities either by dictating the distribution of cyclic species in complex mixtures or by ruling the competition between the intra- and intermolecular versions of a noncovalent interaction.
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