期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 144, 期 23, 页码 10180-10185出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.1c13537
关键词
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资金
- European Research Council [692981]
- Italian Ministry of University and Research [FARE R16S9XXKX3, PRIN 20173L7W8K, PRIN 201732PY3X]
- European Research Council (ERC) [692981] Funding Source: European Research Council (ERC)
This study describes a [2]rotaxane that can autonomously and reversibly shuttle the ring away from equilibrium under light irradiation through a network of E/Z isomerization and proton transfer reactions.
We describe a [2]rotaxane whose recognition sites for the ring are a dibenzylammonium moiety, endowed with acidic and H-bonding donor properties, and an imidazolium center bearing a photoactive phenylazo substituent. Light irradiation of this compound triggers a network of E/Z isomerization and proton transfer reactions that enable autonomous and reversible ring shuttling away from equilibrium.
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