期刊
JOURNAL OF RAMAN SPECTROSCOPY
卷 53, 期 7, 页码 1333-1341出版社
WILEY
DOI: 10.1002/jrs.6366
关键词
dielectric resonator; ordered perovskite; PC-SOFC; Raman scattering; synchrotron X-ray diffraction
类别
资金
- Ministerio de Ciencia e Innovacion [MAT2017-84496-R]
- Spanish Ministry of Science, Innovation, and Universities
- FAPESP [13/07793-6]
The structural ordering process plays a crucial role in complex perovskites for tuning various physical properties and is essential for designing high-performance devices. In this study, the coexistence of B-site 1:1 and 1:2 order types in mixed ordered A(3)CaNb(2)O(9) perovskite was investigated using Raman spectroscopy and high-resolution synchrotron X-ray powder diffraction. The results showed that Raman spectroscopy can be used as a rapid tool to probe the achievement of ordered, partially ordered, or disordered structures in complex perovskites.
The structural ordering process in complex perovskites has a pivotal role for tuning many physical properties for broad applications, ranging from microwave technology, proton-conduction, multiferroicity, and so on. Therefore, the characterization of order type in these materials is essential for designing new devices with high-performance. Here, the coexistence of B-site 1:1 and 1:2 order types in mixed ordered A(3)CaNb(2)O(9) (A = Ba, Sr) perovskite was investigated by combining Raman spectroscopy and high-resolution synchrotron X-ray powder diffraction. High-wavenumber interval 700-825 cm(-1) exhibits two bands concerning the symmetric breathing modes of [NbO6] octahedra in A(3)CaNb(2)O(9), which were ascribed to the 1:1 and 1:2 domain regions in coexistence. This model was fully corroborated using two phases for describing the synchrotron X-ray pattern of the Ba3CaNb2O9 sample. Therefore, the Raman spectroscopy can be indeed applied as a rapid tool for probing the achievement of ordered, partially ordered, or disordered structures in complex perovskites. For the first time, BaLaCaNbO6 was synthesized and structural characterized, being indexed by the monoclinic unit cell belonging to the space group I2/m$$ I2/m $$.
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