期刊
JOURNAL OF POWER SOURCES
卷 530, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2022.231321
关键词
Cathode; Thermal expansion coefficient; Proton uptake; Cobalt-based perovskite oxides
资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences [XDA2100000]
- National Natural Science Foundation of China [21878158, 21576135, 22108121, 21905295]
The excessive thermal expansion behavior of Co-based electrode often leads to cell degradation or delamination. In this study, a novel single-phase electrode material BSNCF was developed, which showed great stability and performance under harsh thermal cycling conditions.
Nowadays, the excessive thermal expansion behavior of Co-based electrode always leads to the cell degradation or delamination. Especially for BaCoO3-delta-type perovskite oxides, as the result of the large ionic radius of Ba2+ (1.61 angstrom), the phase structures of these materials are not stable. Herein, we developed a novel single-phase electrode Ba2Sc0.1Nb0.1Co1.5Fe0.3O6-delta (BSNCF) with a stable cubic perovskite structure and suitable thermal expansion coefficient (TEC, 11.9 x 10(-6) K-1), which showed a great stability in symmetrical cell area specific resistances (ASRs) subjecting to the harsh thermal cycling procedure with 30 cycles between 300 degrees C and 600 degrees C (increased from 0.197 Omega cm(2) to 0.222 Omega cm(2),13% increase). The high-temperature hard X-ray absorption spectroscopy measurement directly monitored a small change of Co valence in BSNCF as the temperatures rising. Also, BSNCF exhibits well proton uptake for its appropriate oxygen-site basicity and excellent surface reaction activity. The single cell based on BSNCF achieved an outstanding peak power density of 977 mW cm(-2) at 600 degrees C.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据