Forster Resonance Energy Transfer between Fluorescent Organic Semiconductors: Poly(9,9-dioctylfluorene-alt-benzothiadiazole) and 6,13-Bis(triisopropylsilylethynyl)pentacene

In the present study, an investigation of the electronic excitation energy transfer between two p-type fluorescent semiconductors, F8BT [poly(9,9-dioctylfluorene- alcohol- benzothiadiazole] and TIPS-P [6,13- bis-(triisopropylsilylethynyl)pentacene], has been carried out in a chloroform solution using steady-state and time-domain fluorescence techniques. The spectral overlap integral between donor (F8BT) emission and acceptor (TIPS-P) absorption is 2.04 x 10(15) nm(4)/(M cm), and the corresponding critical transfer distance is 53.12 angstrom. In donor decay dynamics, at the lower acceptor concentrations, the observed results deviate from the Forster theory due to the combined effect of diffusion and energy migration. However, it does not exhibit energy migration and distribution for higher acceptor concentrations, and the system follows the Forster model of resonance excitation energy transfer (FRET). The higher value of the donor-acceptor interaction strength than self-interaction (donor-donor interaction) appears to be responsible for this behavior. Further, in acceptor decay, the appearance of the rise time and its decrease with the acceptor concentration confirms FRET from F8BT to TIPS-P.

Automated summary

In this study, the electronic excitation energy transfer between two p-type fluorescent semiconductors, F8BT and TIPS-P, was investigated in a chloroform solution using fluorescence techniques. It was found that the deviation from the Förster theory at lower acceptor concentrations is a result of diffusion and energy migration, while the system follows the Förster model of resonance excitation energy transfer at higher acceptor concentrations. The appearance of rise time and its decrease with acceptor concentration confirms FRET from F8BT to TIPS-P.