期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 688, 期 -, 页码 140-148出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2016.07.184
关键词
Sulfonated graphene; Polypyrrole; Composite; Supercapacitor; Electrodeposition
资金
- National Natural Science Foundation of China [21175068, 21177044]
- Jiangsu Agricultural Science and Technology Innovation Fund Project [CX(14)2127]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Jiangsu Collaborative Innovation Center of Biomedical Functional Materials
A sulfonated graphene/polypyrrole (s-G/PPy) composite was successfully prepared by a method of one-step electrodeposition using water soluble sulfonated graphene (s-G) and polypyrrole as the starting materials. The morphology, structure and thermal stability of s-G/PPy were characterized using transmission electron microscope, scanning electron microscope, thermogravimetric analysis, and Raman spectroscopy. The electrochemical performance of s-G/PPy is evaluated with galvanostatic charge/discharge, cyclic voltammetry and electrochemical impedance spectroscopy in 1 mol L-1 KCl. The composite exhibits high specific capacitance and good cycling stability. The specific capacitance of s-G/PPy is as high as 310 F g(-1) at a current density of 0.3 A g(-1) and retains 71% after 1500 cycles at a scan rate of 50 mV s(-1). The equivalent series resistance of s-G/PPy film is only 0.6 Omega. In addition, a s-G/PPy//s-G/PPy symmetric supercapacitor was also fabricated and in which the s-G/PPy showed specific capacitance still up to 253 F g(-1). (C) 2016 Elsevier B.V. All rights reserved.
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