期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 7, 页码 4883-4893出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c00237
关键词
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资金
- Special Research Fund (BOF) of Ghent University [01D14919]
- CSC
- Research Foundation-Flanders (FWO) [11I6921N, G099319N]
A simple and efficient method for oxidative coupling of terminal alkynes using imidazol(in)ium aurates as pre-catalysts is reported. It shows high functional group tolerance and leads to a broad range of 1,3-diyne compounds in moderate to excellent yields using low catalyst loading and mild conditions.
A simple and efficient method for the oxidativecoupling of terminal alkynes is reported for thefirst time, makinguse of imidazol(in)ium aurates as pre-catalysts. This approachdisplays high functional group tolerance and leads to a broad rangeof 1,3-diyne compounds in moderate to excellent yields using lowcatalyst loading and is performed in air under mild and sustainable conditions.
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