期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 16, 页码 10564-10575出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c02632
关键词
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资金
- Science and Engineering Research Board (SERB) , New Delhi, India [EEQ/2018/000156]
- University Grants Commission (UGC)
- Department of Science and Technology-Fund for Improvement of Science and Technology (DST-FIST)
Functionalization of carboxylic acids using sulfoxonium ylides in the presence of [VO(acac)(2)] as a catalyst is reported. Compared to the usual carbene source, diazo compounds, sulfoxonium ylides were found to produce alpha-carbonyloxy esters in better yield. Various standard spectroscopic and analytical techniques were utilized to characterize the formed products.
Functionalization of carboxylic acids using sulfoxo-nium ylides in the presence of [VO(acac)(2)] as a catalyst is reported. The usual carbene source, diazo compounds, failed to produce alpha-carbonyloxy esters in good yield when compared to sulfoxonium ylides. Various standard spectroscopic and analytical techniques were used to characterize the products formed.
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