期刊
JOURNAL OF NUCLEAR MATERIALS
卷 561, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jnucmat.2022.153521
关键词
Cluster dynamics simulation; Zirconium alloys; Hydride formation; Irradiation
This study investigates the formation of delta hydrides in zirconium cladding under radiation and thermal aging conditions through rate theory modeling. The preferential nucleation of platelet-shaped hydrides on grain boundaries was observed, and the importance of this modification in the precipitation model was analyzed. Comparisons of different approaches were made to understand the factors affecting hydride formation in the clad.
A B S T R A C T The delta hydrides formation in zirconium cladding under irradiation and thermal aging is studied by the rate theory modeling. The precipitates may lead to cracking of the clad and are investigated both exper-imentally and theoretically. The rate theory studies published so far are based on the well-established classical nucleation theory, but use several assumptions, e.g. of homogeneous hydride nucleation mode and spherical shape of precipitates, which contradict observations. In this work we continue the develop-ment of the hydride precipitation model by taking into consideration the observed preferential nucleation of the platelet-shaped hydrides on grain boundaries, and analyze the importance of such modifications by comparing calculations performed with different approaches. We also extract information from the literature on the hydrogen solution energy and alpha Zr / delta hydride interface energy, which define the hydrogen-hydride binding energy as a function of precipitate size, and show that the observed hy-dride size and density are well described with the use of the capillary approximation. The difference in precipitation kinetics during thermal annealing of samples with pre-existing level of hydrogen and under irradiation to the same final hydrogen concentration is elucidated. This improves our understanding of the factors affecting hydride formation in the clad.Published by Elsevier B.V.
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