期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 669, 期 -, 页码 146-155出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2016.01.251
关键词
RGO/CoAl-layered double hydroxide; Electrostatic self-assembly; Hydrothermal reduction; Supercapacitor
资金
- National Natural Science Foundation of China [21273085, 51578556]
- Natural Science Foundation of Guangdong Province, China [2015A030313376, 2015A030308005]
- Scientific and Technological Plan of Guangdong Province [2014A020216009, 2015A040404043]
Graphene oxide/CoAl-layered double hydroxide (GO/CoAl-LDHs) composites were successfully prepared by a face-to-face electrostatic self-assembly method. Positively charged colloidal CoAl-LDHs nanosheets (CoAl-LDH-NS) and negatively charged colloidal GO nanosheets were uniformly mixed; then CoAl-LDHNS were assembled on GO nanosheets via electrostatic attraction to prepare GO/CoAl-LDHs composites. The GO/CoAl-LDHs composites were then transformed to the reduced graphene oxide/CoAl-layered double hydroxide (RGO/CoAl-LDHs) composites with a hydrothermal method. The results showed that the content of RGO has a remarkable influence on the capacitive properties of composites. Among the composites with different RGO content, the RGO/CoAl-LDHs composite containing 12.0 wt% RGO displayed a maximum specific capacitance of 825 F g(-1) at low current density of 1 A g(-1), while that of pure CoAl-LDHs was 552 F g(-1). The capacitance retention of the RGO/CoAl-LDHs composite from 1 A g(-1) to 8 A g(-1) is found to be 62.3%, whereas that of pure CoAl-LDHs is only 31.9%. Face-to-face self-assembling between positively charged CoAl-LDH-NS and negatively charged GO nanosheets can effectively reduce the self-agglomeration of GO nanosheets and avoid CoAl-LDH-NS stacking together, which lead to improvement of the capacitive performance. (C) 2016 Elsevier B.V. All rights reserved.
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