期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1257, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2022.132537
关键词
Fluoride ion probe; Triarylboron; Intramolecular charge transfer state; Local excited state
资金
- National Natural Science Foundation of China [51703035]
- Guangdong Basic and Applied Basic Research Foundation [2019B1515120035]
Triarylboron/acridine hybrids with donor-acceptor structures were designed and synthesized. By modifying the acridine with additional phenyl groups, a novel compound was used as a fluorescent probe for detecting fluoride ion. The modified compound exhibited intense deep-blue emission when reacted with F-. The deep-blue emission originates from the phenyl modified DMAc groups, which expands the pi conjugate system.
Triarylboron/acridine hybrids bearing donor-acceptor structures were designed and synthesized. After simply modifying the acridine with additional phenyl groups, the novel compound was utilized as fluorescent probe for the detection of fluoride ion. The original green emission was quenched and intense deep-blue emission emerged simultaneously when reacted with F-. According to the DFT calculation result, the deep-blue emission originates from the phenyl modified DMAc groups that expand the pi conjugate system of electronic delocalization. Based on the fluorescence spectra intensity variation of deepblue emission with different concertation of F-, the detection limit of the probe is approximately 10(-8) M, which is decreased by two orders of magnitude compared with that of the non-phenyl group modified counterpart. The turn off/turn on property endows the probe with high sensitivity, good selectivity and reversibility. (C) 2022 Elsevier B.V. All rights reserved.
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