期刊
JOURNAL OF MOLECULAR LIQUIDS
卷 354, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molliq.2022.118892
关键词
Nanofluid; Stability; Deep Eutectic Solvent; MWCNT; MD
资金
- Science and Engineering Research Board, Government of India [CRG/2018/000522]
In this study, a thermal media was synthesized and a corresponding nanofluid was prepared using MWCNT dispersed in a base fluid. The morphology and crystallinity of MWCNT were characterized, and the stability of the nanofluid was confirmed through visual observation and zeta potential measurements. The thermophysical properties of the nanofluid were measured, and Molecular Dynamic simulations were performed to validate the results.
In this study, a thermal media is synthesized by mixing hydrogen bond acceptor (HBA) [Methyltriphenylphosphonium bromide (MTPB)] salt with hydrogen bond donor (HBD) [ethylene glycol] at a molar ratio of 1:4. Thereafter the corresponding nanofluid was prepared by dispersing 0.02 wt% Multi-Walled Carbon Nanotube (MWCNT) having a diameter 10-30 nm in the base fluid. Prior to dispersion, the shape and morphology of the MWCNT were ascertained using both Field Emission Scanning Electron Microscope (FESEM) and Field Emission Transmission Electron Microscope (FETEM). The crystallinity and functional groups were investigated by X-ray Powder Diffraction meter (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). The stability of the prepared nanofluid was initially performed using visual observation followed by zeta potential measurements. Thermogravimetric analysis (TGA) was performed to check the stability of nanofluid at a temperature close to 500 degrees C at a heating rate of 10 degrees C/min under nitrogen environment. Thermophysical properties such as density, viscosity, thermal conductivity, and specific heat of nanofluid were measured in the temperature range 25-85 degrees C. It is evident from the experimental data that viscosity and density decrease with an increase in temperature. On the contrary, the specific heat and thermal conductivity of the nanofluid were found to increase with temperature. This is due to the induced Brownian motion of the nanoparticle, which results in higher kinetic energy at high temperature. In the penultimate section, Molecular Dynamic (MD) simulations were performed to compare and validate the results of thermal conductivity of nanofluid.(c) 2022 Elsevier B.V. All rights reserved.
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