FeNi@CNS nanocomposite as an efficient electrochemical catalyst for N2 -to-NH3 conversion under ambient conditions

The electrocatalytic nitrogen reduction reaction (NRR) has emerged as a promising renewable energy source and a feasible strategy as an alternative to Haber-Bosch ammonia (NH3) synthesis. However, finding an efficient and cost-effective robust catalyst to activate and cleave the extremely strong triple bond in nitrogen (N-2) for electrocatalytic NRR is still a challenge. Herein, a FeNi@CNS nanocomposite as an efficient catalyst for N-2 fixation under ambient conditions is designed. This FeNi@CNS nanocomposite was prepared by a simple water bath process and post-calcination. The FeNi@CNS is demonstrated to be a highly efficient NRR catalyst, which exhibits better NRR performance with exceptional Faradaic efficiency of 9.83% and an NH3 yield of 16.52 mu g h(-1) cm(-2) in 0.1 M Na2SO4 aqueous solution. Besides, high stability and reproducibility with consecutive 6 cycles for two hours are also demonstrated throughout the NRR electrocatalytic process for 12 h. Meanwhile, the FeNi@CNS catalyst encourages N-2 adsorption and activation as well as effectively suppressing competitive HER. Therefore, this earth-abundant FeNi@CNS catalyst with a subtle balance of activity and stability has excellent potential in NRR industrial applications. (C)2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

This study designed a FeNi@CNS nanocomposite as an efficient nitrogen reduction catalyst, which showed excellent performance and stability under ambient conditions. The catalyst exhibited remarkable NRR activity, promoted N-2 adsorption and activation, and effectively suppressed competitive HER. Therefore, the FeNi@CNS catalyst has significant potential in industrial applications of nitrogen reduction.