期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 104, 期 -, 页码 8-18出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2021.06.067
关键词
Ultra-coarse cemented carbides; High-temperature compressive behavior; Strengthening of hard-phase grains; Dislocation motion
资金
- National Key Program of Research and Development [2018YFB0703902]
- National Natural Science Foundation of China [51631002, 51621003, 52101003, 52171061, U20A20236]
This study proposes a method to enhance the high temperature compression strength of ultra-coarse cemented carbides by modulating hard matrix grains using activated TaC nanoparticles, through solid solution strengthening of Ta atoms. The mechanisms of Ta dissolution in WC crystal and strengthening of ultra-coarse grains through interaction with dislocations were revealed at the atomic scale.
Ultra-coarse grained cemented carbides are often used under conditions of concurrently applied stress and high temperature. Improvement of high-temperature mechanical performance of ultra-coarse grained cemented carbides is highly desirable but still a big challenge. In this study, it is proposed that the high temperature compression strength of ultra-coarse cemented carbides can be enhanced by modulating hard matrix grains by activated TaC nanoparticles, through solid solution strengthening of Ta atoms. Based on the designed experiments and microstructural characterizations combined with finite element simulations, the grain morphology, stress distribution and dislocation configuration were studied in detail for ultra-coarse grained cemented carbides. The mechanisms of Ta dissolving in WC crystal and strengthening ultra-coarse grains through interaction with dislocations were disclosed from the atomic scale. This study opens a new perspective to modulate hard phases of cemented carbides for improving their high temperature performance, which will be applicable to a variety of cermet and ceramic-based composite materials. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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