期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 102, 期 -, 页码 66-71出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2021.06.028
关键词
HE-amorphous ribbons; Magnetocaloric performances; Rare earths; Magnetic properties; Giant refrigerant capacity
资金
- National Natural Sci-ence Foundation of China [52071197]
- Science and Technol-ogy Committee of Shanghai Municipality [19ZR1418300, 19DZ2270200]
- Independent Research and Development Project of State Key Laboratory of Advanced Special Steel , Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University [SKLASS 2020-Z06]
Magnetic refrigeration is a highly promising solid state environmentally friendly and high-efficiency alternative method to gas compression cooling. This study investigates the microstructure, magnetic, and magnetocaloric properties of a quinary high-entropy amorphous alloy Er20Ho20Gd20Ni20Co20. The alloy exhibits excellent cryogenic magnetocaloric performances and is suitable for cryogenic magnetic refrigeration applications.
Magnetic refrigeration (MR) by utilizing the magnetocaloric (MC) effect is recognized as one of the most potential promising solid state environmentally friendly and high efficiency alternative method to the well-used state-of-the-art gas compression cooling technique. In this work, a systematic investigation of quinary equi-atomic rare-earths (RE) based Er20Ho20Gd20Ni20Co20 high-entropy (HE) amorphous alloy in terms of the microstructure, magnetic and magnetocaloric (MC) properties have been reported. The Er20Ho20Gd20Ni20Co20 exhibits promising glass forming ability with an undercooled liquid region of 72 K. Excellent cryogenic MC performances can be found in wide temperature from similar to 25 and similar to 75 K, close to H-2 and N-2 liquefaction, respectively. Apart from the largest magnetic entropy change (similar to Delta S-M) reaches 17.84 J/(kg K) with 0-7 T magnetic field change, corresponding refrigerant capacity (RC) attains a giant value of 1030 J/kg. The promising cryogenic MC performances together with the unique HE amorphous characterizations make the quinary Er20Ho20Gd20Ni20Co20 amorphous alloy attractive for cryogenic MR applications. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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