期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 32, 期 6, 页码 2235-2248出版社
SPRINGER
DOI: 10.1007/s10904-022-02287-z
关键词
Graphene oxide; Functionalized; Nanocomposites; Wastewater; Adsorption; Nano-adsorbent
资金
- Institute for Nanotechnology and Water Sustainability, University of South Africa
In this study, magnetic graphene oxide was synthesized and used for the adsorption of three heavy metals. The magnetic graphene oxide was prepared by coupling magnetic nanosilica with graphene oxide using (3-aminopropyl) triethoxysilane as a functionalizing agent. The experimental results showed that the Fe3O4@SiO2-NH2/GO nanoadsorbents exhibited excellent adsorption performance and stability.
(3-Aminopropyl) triethoxysilane (APTES) modified magnetic graphene oxide was synthesized and applied in the adsorption of three heavy metals, Pb(II), Cd(II) and Ni(II) from aqueous solution. An approach to prepare magnetic GO was adopted by using (3-aminopropyl) triethoxysilane (APTES) as a functionalizing agent on magnetic nanosilica coupled with GO to form the Fe3O4@SiO2-NH2/GO nanocomposite. FT-IR, XRD, BET, UV, VSM, SAXS, SEM and TEM were used to characterize the synthesized nanoadsorbents. Batch adsorption studies were conducted to investigate the effect of solution pH, initial metal ion concentration, adsorbent dosage and contact time. The maximum equilibrium time was found to be 30 min for Pb(II), Cd(II) and 60 min for Ni(II). The kinetics studies showed that the adsorption of Pb(II), Cd(II) and Ni(II) onto Fe3O4@SiO2-NH2/GO followed the pseudo-second-order kinetics. All the adsorption equilibrium data were well fitted to Langmuir isotherm model and maximum monolayer adsorption capacity for Pb(II), Cd(II) and Ni(II) were 13.46, 18.58 and 13.52 mg/g, respectively. The Fe3O4@SiO2-NH2/GO adsorbents were reused for at least 7 cycles without the leaching of mineral core, showing the enhanced stability and potential application of Fe3O4@SiO2-NH2/GO adsorbents in water/wastewater treatment.
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