Adsorption of dyes methyl violet and malachite green from aqueous solution on multi-step modified rice husk powder in single and binary systems: Characterization, adsorption behavior and physical interpretations

A novel modified rice husk (MRH) has been prepared for removing cationic dyes in both single system and binary system. SEM-EDS, FT-IR, XRD and XPS were used to characterize the physical and chemical properties of MRH. It showed that the maximum adsorption capacity of MRH for methyl violet (MV) and malachite green (MG) in single system was 154.49 and 996.97 mg g(-1), while in binary system was 530.94 and 408.58 mg g(-1), respectively. The experimental results showed that the pseudo-second-order kinetic model was better to describe the kinetic behavior of MV and MG adsorption. By using double layer adsorption model, we found that the n D for MV adsorption were 2.52, 2.65 and 3.34 at 298, 308 and 318 K, respectively, and the n D for MG adsorption were 4.59, 4.85 and 4.30, respectively. These results illustrated that multiple dye molecules were adsorbed on one adsorption site in non-parallel direction, indicating that the adsorption of dyes is multi-molecular mechanism. Furthermore, synergistic and antagonistic adsorption might be existed simultaneously in binary system. In summary, MRH has been shown well adsorption properties and reusability and our finding might provide a new idea for developing low-cost, efficient and reusable adsorbent to remove dyes from wastewater.

Automated summary

A novel modified rice husk (MRH) was prepared as an adsorbent for removing cationic dyes. The MRH showed high adsorption capacity for methyl violet (MV) and malachite green (MG), both in single and binary systems. The adsorption kinetics and mechanism were investigated, revealing a multi-molecular mechanism with non-parallel adsorption directions. Additionally, synergistic and antagonistic effects were observed in the binary system. This study provides a new approach for developing low-cost, efficient, and reusable adsorbents for dye removal.